copper 5-(2-((((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)methylene)oxy)carbonyl)phenyl)-10,15,20-tritolylporphyrin

Base Information

• Chemical Name: copper 5-(2-((((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)methylene)oxy)carbonyl)phenyl)-10,15,20-tritolylporphyrin
• CAS No.: 78280-10-1
• Molecular Formula: C₅₇H₅₀CuN₅O₂
• Molecular Weight: 900.602
• Mol file: 78280-10-1.mol

Synonyms:

Chemical Property of copper 5-(2-((((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)methylene)oxy)carbonyl)phenyl)-10,15,20-tritolylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of copper 5-(2-((((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)methylene)oxy)carbonyl)phenyl)-10,15,20-tritolylporphyrin

There total 2 articles about copper 5-(2-((((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)methylene)oxy)carbonyl)phenyl)-10,15,20-tritolylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

3-(hydroxymethyl)-2,2,5,5-tetramethylpyrrolidinyl-1-oxy (27298-75-5) + CuN4C20H8(C6H4CH3)3C6H4COCl (78280-19-0) → copper 5-(2-((((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)methylene)oxy)carbonyl)phenyl)-10,15,20-tritolylporphyrin (78280-10-1)

Guidance literature:

In tetrahydrofuran; pyridine; refluxing for 3 h; evapn., chromy. on silica gel (CHCl3), recrystn. from CHCl3/heptane; elem. anal.;

DOI:10.1021/ic50224a042

Reference yield:

copper 5-(2-carboxyphenyl)-10,15,20-tritolylporphyrin (73469-15-5) → copper 5-(2-((((2,2,5,5-tetramethyl-1-oxypyrrolidin-3-yl)methylene)oxy)carbonyl)phenyl)-10,15,20-tritolylporphyrin (78280-10-1)

Guidance literature:

Multi-step reaction with 2 steps

1: oxalyl chloride / benzene

2: tetrahydrofuran; pyridine

With oxalyl chloride; In tetrahydrofuran; pyridine; benzene;

DOI:10.1021/ic50224a042

upstream raw materials:

3-(hydroxymethyl)-2,2,5,5-tetramethylpyrrolidinyl-1-oxy

CuN₄C₂₀H₈(C₆H₄CH₃)3C₆H₄COCl

copper 5-(2-carboxyphenyl)-10,15,20-tritolylporphyrin