[Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]

Base Information

Chemical Name:[Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]
CAS No.:916600-82-3
Molecular Formula:C₃₁H₂₃F₃Fe₂O₄
Molecular Weight:628.21
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]

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Technology Process of [Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]

There total 1 articles about [Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: [(η(5)-C9H7)(CO)2Fe]2

: 368-39-8
triethyloxonium fluoroborate

: 2786-01-8
(4-trifluoromethylphenyl)lithium

: 916600-82-3
[Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]

Guidance literature:: In diethyl ether; under N2 atm. to suspn. Fe complex in ether at -40°C soln. ArLi in ether was added and stirred at -40 to -20°C for 3 h, soln. was evapd. in vacuo at -20°C, Et3OBF4 was added, react. mixt. was dissolved in water at 0°C; react. mixt. was extd. with petroleum ether - CH2Cl2 (5:1), solvent was removed in vacuo, chromy. on alumina at -25°C (petroleum ether - CH2Cl2 3:1), solvent was removed, recrystn. from petroleum ether - CH2Cl2 (10:1) at -80°C; elem. anal.;
DOI:10.1016/j.jorganchem.2006.07.012

Reference yield: 85.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 916600-82-3
[Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]

: [Fe2(μ-CC6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]BF4

Guidance literature:: In diethyl ether; under N2 atm. to soln. Fe complex in ether at -60°C HBF4*OEt2 wasadded and stirred at -60 to -30°C for 1 h; ppt. was filtered. washed with ether at -60°C and dried in vacuo at -30°C;
DOI:10.1016/j.jorganchem.2006.07.012

Reference yield: 80.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 16940-66-2
sodium tetrahydroborate

: 916600-82-3
[Fe2(μ-C(OC2H5)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]

: [Fe2(μ-C(H)C6H4CF3-p)(μ-CO)(CO)2(η5-C9H7)2]

Guidance literature:: In tetrahydrofuran; under N2 atm. to soln. Fe complex in THF (generated in situ by treatmentwith HBF4*Et2O) at -80°C NaBH4 was added and stirred at -80 to - 40°C for 3 h; soln. was evapd. in vacuo at -40°C to dryness, residue was chromd. on alumina column at -20°C (petroleum ether - CH2Cl2 2:1), solvent was removed, residue was recrystd. from petroleum ether - CH2Cl2 at -80°C; elem. anal.;
DOI:10.1016/j.jorganchem.2006.07.012