2,4,6-Trimethylbenzene-1-tellurol

Base Information

• Chemical Name: 2,4,6-Trimethylbenzene-1-tellurol
• CAS No.: 134847-97-5
• Molecular Formula: C9H12Te
• Molecular Weight: 247.794
• DSSTox Substance ID: DTXSID60768199
• Mol file: 134847-97-5.mol

Synonyms:2,4,6-Trimethylbenzene-1-tellurol;134847-97-5;DTXSID60768199

Chemical Property of 2,4,6-Trimethylbenzene-1-tellurol

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 248.9922981
• Heavy Atom Count: 10
• Complexity: 99.3

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC(=C(C(=C1)C)[Te])C

Technology Process of 2,4,6-Trimethylbenzene-1-tellurol

There total 2 articles about 2,4,6-Trimethylbenzene-1-tellurol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mesityltellurolate lithium (92720-47-3) → mesitylene tellurol (134847-97-5)

Guidance literature:

With tetrafluoroboric acid diethyl ether; In Petroleum ether; at -20 ℃; Yield given;

Reference yield:

dimesityl ditelluride (92720-46-2) → mesitylene tellurol (134847-97-5)

Guidance literature:

Multi-step reaction with 2 steps

1: LiBHEt₃ / tetrahydrofuran / 0.25 h / -78 °C

2: HBF₄*Et₂O / petroleum ether / -20 °C

With tetrafluoroboric acid diethyl ether; lithium triethylborohydride; In tetrahydrofuran; Petroleum ether;

Reference yield: 65.0%

mesitylene tellurol (134847-97-5) + bis(hexamethyldisilylamido)mercury(II) → Hg(2+)*2(TeC6H2(CH3)3)(1-) = Hg(TeC6H2(CH3)3)2

Guidance literature:

In Petroleum ether; byproducts: HN(SiMe3)2; under Ar, at -20°C; filtration at room temp., recrystn. from hot toluene;

DOI:10.1039/DT9910002325

upstream raw materials:

mesityltellurolate lithium

dimesityl ditelluride

Downstream raw materials:

1,1,1,3,3,3-hexamethyl-disilazane

[Zn(TeC₆H₂(CH₃)3)2(P(CH₃)3)]

[Zn(TeC₆H₂(CH₃)3)2(C₅H₅N)2]

[Zn(TeC₆H₂(CH₃)3)2(P(CH₃)3)2]