[(4-Ethenylphenyl)ethynyl](trimethyl)silane

Base Information

Chemical Name:[(4-Ethenylphenyl)ethynyl](trimethyl)silane
CAS No.:135005-24-2
Molecular Formula:C13H16Si
Molecular Weight:200.356
Hs Code.:
DSSTox Substance ID:DTXSID90579750
Nikkaji Number:J871.286G
Wikidata:Q82470363
Mol file:135005-24-2.mol

Synonyms:135005-24-2;[(4-Ethenylphenyl)ethynyl](trimethyl)silane;4-trimethylsilylethynylstyrene;DTXSID90579750;G15694;TRIMETHYL((4-VINYLPHENYL)ETHYNYL)SILANE

Suppliers and Price of [(4-Ethenylphenyl)ethynyl](trimethyl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of [(4-Ethenylphenyl)ethynyl](trimethyl)silane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:200.102127045
Heavy Atom Count:14
Complexity:250

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Si](C)(C)C#CC1=CC=C(C=C1)C=C

Technology Process of [(4-Ethenylphenyl)ethynyl](trimethyl)silane

There total 7 articles about [(4-Ethenylphenyl)ethynyl](trimethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 1066-54-2
trimethylsilylacetylene

: 135005-24-2
[(4-ethenylphenyl)ethynyl]trimethylsilane

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; at 50 ℃; for 12h; Inert atmosphere;
DOI:10.1002/anie.201612585

Reference yield: 81.0%

: 6396-08-3,139618-18-1
triphenylphosphine hydrogen iodide

: 77123-57-0
4-[(trimethylsilyl)ethynyl]bezaldehyde

: 135005-24-2
[(4-ethenylphenyl)ethynyl]trimethylsilane

Guidance literature:: triphenylphosphine hydrogen iodide; With n-butyllithium; In tetrahydrofuran; hexane; at -10 - 20 ℃; for 1.5h;

4-[(trimethylsilyl)ethynyl]bezaldehyde; In tetrahydrofuran; hexane; at -20 - 20 ℃;
DOI:10.1021/jo061481t

Reference yield: 70.0%

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 1066-54-2
trimethylsilylacetylene

: 135005-24-2
[(4-ethenylphenyl)ethynyl]trimethylsilane

: (E)-1-(4-vinylphenyl)-2,4-bis(trimethylsilyl)but-1-en-3-yne

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; triethylamine; In toluene; at 110 ℃; for 24h; stereoselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1016/j.tet.2018.09.013