(1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.0^3,8]pentadeca-3⁽⁸⁾,4,6,11-tetraen-13-one

Base Information

• Chemical Name: (1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.0^3,8]pentadeca-3⁽⁸⁾,4,6,11-tetraen-13-one
• CAS No.: 219523-50-9
• Molecular Formula: C₂₇H₃₂O₆S
• Molecular Weight: 484.613

Synonyms:

Chemical Property of (1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.0^3,8]pentadeca-3⁽⁸⁾,4,6,11-tetraen-13-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.0^3,8]pentadeca-3⁽⁸⁾,4,6,11-tetraen-13-one

There total 3 articles about (1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.0^3,8]pentadeca-3⁽⁸⁾,4,6,11-tetraen-13-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol (219523-48-5) → (1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.03,8]pentadeca-3(8),4,6,11-tetraen-13-one (219523-50-9)

Guidance literature:

With potassium fluoride; dihydroxy-methyl-borane; hydrogen fluoride; titanium tetrachloride; Yield given. Multistep reaction;

DOI:10.1016/S0960-894X(98)00539-3

Reference yield:

(S)-1-Hydroxy-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enecarbaldehyde (162084-46-0) → (1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.03,8]pentadeca-3(8),4,6,11-tetraen-13-one (219523-50-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) t-BuMgCl

2: 1.) MeB(OH)2, 2.) TiCl₄, 3.) HF, KF

With potassium fluoride; dihydroxy-methyl-borane; hydrogen fluoride; tert-butylmagnesium chloride; titanium tetrachloride;

DOI:10.1016/S0960-894X(98)00539-3

Reference yield:

C10H11LiO3 → (1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.03,8]pentadeca-3(8),4,6,11-tetraen-13-one (219523-50-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.) t-BuMgCl

2: 1.) MeB(OH)2, 2.) TiCl₄, 3.) HF, KF

With potassium fluoride; dihydroxy-methyl-borane; hydrogen fluoride; tert-butylmagnesium chloride; titanium tetrachloride;

DOI:10.1016/S0960-894X(98)00539-3

upstream raw materials:

(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

(S)-1-Hydroxy-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enecarbaldehyde

Downstream raw materials:

C₄₁H₄₀O₈S

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