(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

Base Information

Chemical Name:(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol
CAS No.:219523-48-5
Molecular Formula:C₃₆H₅₂O₆SSi
Molecular Weight:640.957
Hs Code.:

(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

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Chemical Property of (S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

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Technology Process of (S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

There total 1 articles about (S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 162084-46-0
(S)-1-Hydroxy-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enecarbaldehyde

: C₁₀H₁₁LiO₃

: 219523-48-5
(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

Guidance literature:: With tert-butylmagnesium chloride; Yield given. Multistep reaction;
DOI:10.1016/S0960-894X(98)00539-3

Reference yield:

: 219523-48-5
(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

: 219523-50-9
(1S,2S,9R,10R)-1,2-Dihydroxy-9-(2-hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.0^3,8]pentadeca-3⁽⁸⁾,4,6,11-tetraen-13-one

Guidance literature:: With potassium fluoride; dihydroxy-methyl-borane; hydrogen fluoride; titanium tetrachloride; Yield given. Multistep reaction;
DOI:10.1016/S0960-894X(98)00539-3

Reference yield:

: 219523-48-5
(S)-1-[(S)-(2-[1,3]Dioxolan-2-yl-6-methoxy-phenyl)-hydroxy-methyl]-4,6,6-trimethyl-5-[1-phenylsulfanyl-meth-(E)-ylidene]-3-triisopropylsilanyloxy-cyclohex-3-enol

: (1S,2S,9R,10R,13S)-9-(2-Hydroxy-ethoxy)-4-methoxy-12,15,15-trimethyl-10-phenylsulfanyl-tricyclo[9.3.1.0^3,8]pentadeca-3⁽⁸⁾,4,6,11-tetraene-1,2,13-triol

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) MeB(OH)2, 2.) TiCl₄, 3.) HF, KF

2: 79 percent / DIBAL

With potassium fluoride; dihydroxy-methyl-borane; hydrogen fluoride; titanium tetrachloride; diisobutylaluminium hydride;
DOI:10.1016/S0960-894X(98)00539-3