sodium trans-3-(4-phenoxybenzoyl)glycidate

Base Information

• Chemical Name: sodium trans-3-(4-phenoxybenzoyl)glycidate
• CAS No.: 83537-42-2
• Molecular Formula: C₁₆H₁₁O₅*Na
• Molecular Weight: 306.25
• Mol file: 83537-42-2.mol

Synonyms:

Chemical Property of sodium trans-3-(4-phenoxybenzoyl)glycidate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of sodium trans-3-(4-phenoxybenzoyl)glycidate

There total 3 articles about sodium trans-3-(4-phenoxybenzoyl)glycidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

ethyl trans-3-(4-phenoxybenzoyl)glycidate (83537-52-4,94402-83-2) → sodium trans-3-(4-phenoxybenzoyl)glycidate (83537-42-2,94402-96-7) + cis-3-3-(4-phenoxybenzoyl)glycidic acid (83537-46-6,94402-56-9,94402-95-6)

Guidance literature:

With sodium hydrogencarbonate; In ethanol; water; for 2h; Heating;

DOI:10.1248/cpb.32.3066

Reference yield:

diphenylether (101-84-8) → sodium trans-3-(4-phenoxybenzoyl)glycidate (83537-42-2,94402-96-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 60 percent / AlCl₃ / CS₂ / 6 h / Ambient temperature

2: 55.7 percent / NaOEt / ethanol / 2 h / Ambient temperature

3: 80 percent / NaHCO₃ / H₂O; ethanol / 2 h / Heating

With aluminium trichloride; sodium ethanolate; sodium hydrogencarbonate; In carbon disulfide; ethanol; water;

DOI:10.1248/cpb.32.3066

Reference yield:

2-chloro-1-(4-(phenoxy)phenyl)ethanone (13075-63-3) → sodium trans-3-(4-phenoxybenzoyl)glycidate (83537-42-2,94402-96-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 55.7 percent / NaOEt / ethanol / 2 h / Ambient temperature

2: 80 percent / NaHCO₃ / H₂O; ethanol / 2 h / Heating

With sodium ethanolate; sodium hydrogencarbonate; In ethanol; water;

DOI:10.1248/cpb.32.3066

upstream raw materials:

ethyl trans-3-(4-phenoxybenzoyl)glycidate

diphenylether

2-chloro-1-(4-(phenoxy)phenyl)ethanone

Downstream raw materials:

2-isopentyl trans-3-(4-phenoxybenzoyl)glycidate

allyl trans-3-(4-phenoxybenzoyl)glycidate

Refernces