RuHCl[diphenyl(2-methoxyethyl)phosphine-P]2[diphenyl(2-methoxyethyl)phosphine-O,P]

Base Information

Chemical Name:RuHCl[diphenyl(2-methoxyethyl)phosphine-P]2[diphenyl(2-methoxyethyl)phosphine-O,P]
CAS No.:111557-09-6
Molecular Formula:C₄₅H₅₂ClO₃P₃Ru
Molecular Weight:870.35
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of RuHCl[diphenyl(2-methoxyethyl)phosphine-P]2[diphenyl(2-methoxyethyl)phosphine-O,P]

Chemical Property:

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Technology Process of RuHCl[diphenyl(2-methoxyethyl)phosphine-P]2[diphenyl(2-methoxyethyl)phosphine-O,P]

There total 1 articles about RuHCl[diphenyl(2-methoxyethyl)phosphine-P]2[diphenyl(2-methoxyethyl)phosphine-O,P] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 16940-66-2
sodium tetrahydroborate

: 109011-62-3
trans-dichlorobis((2-methoxyethyl)diphenylphosphine-O,P)ruthenium(II)

: 68899-50-3
(2-methoxyethyl)diphenylphosphine

: 111557-09-6
trans-dihydridotris((2-methoxyethyl)diphenylphosphine-P;P;O,P)ruthenium(II)

Guidance literature:: In methanol; benzene; to a soln. of the Ru complex and 1 equiv. of Ph2PCH2CH2OCH3 in a hydrogen-saturated mixt. of methanol and benzene is added NaBH4 at 20°C; solvent removed in vac. at ambient temp., residue suspended in cold (0°C) methanol, mixt. stirred for 20 min; filtration gives the solid product; vac. drying at 20°C; elem. anal.;

Reference yield: 72.0%

: 111557-09-6
RuHCl[diphenyl(2-methoxyethyl)phosphine-P]2[diphenyl(2-methoxyethyl)phosphine-O,P]

: 536-74-3
phenylacetylene

: 178743-25-4
chloro-bis[diphenyl(2-methoxyethyl)phosphine-P,O](phenylacetylido)ruthenium(II)

Guidance literature:: In diethyl ether; byproducts: H2; Ar-atmosphere; equimolar amts., brief stirring at room temp.; concn., pptn. on cooling below 0°C, collection (filtration), washing (hexane), drying (vac.); elem. anal.;
DOI:10.1016/0022-328X(95)05950-T

Reference yield:

: 75-15-0,12122-00-8
carbon disulfide

: 111557-09-6
RuHCl[diphenyl(2-methoxyethyl)phosphine-P]2[diphenyl(2-methoxyethyl)phosphine-O,P]

: 178743-20-9
chloro-bis[diphenyl(2-methoxyethyl)phosphine-P;O',P'](η(2)-dithioformato)ruthenium(II)

: 178743-19-6
chloro-tris[diphenyl(2-methoxyethyl)phosphine-P](η(2)-dithioformato)ruthenium(II)

Guidance literature:: In hexane; Ar-atmosphere; excess CS2, stirring at room temp. for 10 min (pptn.); collection (filtration), drying (vac.), recrystn. (CH2Cl2/hexane=1:10); total yield 85%; hand sepn. after further recrystn. on hexane diffusion into CH2Cl2 soln.; elem. anal.;
DOI:10.1016/0022-328X(95)05950-T