cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside

Base Information

Chemical Name:cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside
CAS No.:103814-01-3
Molecular Formula:C₂₈H₅₂O₆Si₃
Molecular Weight:568.974
Hs Code.:

Synonyms:

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Chemical Property of cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside

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Technology Process of cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside

There total 9 articles about cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 100-44-7
benzyl chloride

: 103814-01-3
cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 74.5 percent / 50 percent NaH / dimethylformamide

2: 70 percent / cc. HCl / acetic acid / 1 h / Ambient temperature

3: 74 percent / HCl / diethyl ether / 3 h / 0 °C

4: 22 percent / silver triflate / tetrahydrofuran / 0.5 h / 0 °C / dark

5: 61 percent / toluene-p-sulfonic acid / 10 percent Pd/C / methanol / 2 h / 50 °C

6: imidazole / dimethylformamide / 0.5 h / Ambient temperature

With 1H-imidazole; hydrogenchloride; sodium hydride; toluene-4-sulfonic acid; palladium on activated charcoal; silver trifluoromethanesulfonate; In tetrahydrofuran; methanol; diethyl ether; acetic acid; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(88)85091-2

Reference yield:

: 101703-41-7
methyl 2,3,4-tri-O-allyl-6-O-benzyl-α-D-mannopyranoside

: 103814-01-3
cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 70 percent / cc. HCl / acetic acid / 1 h / Ambient temperature

2: 74 percent / HCl / diethyl ether / 3 h / 0 °C

3: 22 percent / silver triflate / tetrahydrofuran / 0.5 h / 0 °C / dark

4: 61 percent / toluene-p-sulfonic acid / 10 percent Pd/C / methanol / 2 h / 50 °C

5: imidazole / dimethylformamide / 0.5 h / Ambient temperature

With 1H-imidazole; hydrogenchloride; toluene-4-sulfonic acid; palladium on activated charcoal; silver trifluoromethanesulfonate; In tetrahydrofuran; methanol; diethyl ether; acetic acid; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(88)85091-2

Reference yield:

: 101703-42-8
1-O-acetyl-2,3,4-tri-O-allyl-6-O-benzyl-α-D-mannopyranoside

: 103814-01-3
cyclohexyl 6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 74 percent / HCl / diethyl ether / 3 h / 0 °C

2: 22 percent / silver triflate / tetrahydrofuran / 0.5 h / 0 °C / dark

3: 61 percent / toluene-p-sulfonic acid / 10 percent Pd/C / methanol / 2 h / 50 °C

4: imidazole / dimethylformamide / 0.5 h / Ambient temperature

With 1H-imidazole; hydrogenchloride; toluene-4-sulfonic acid; palladium on activated charcoal; silver trifluoromethanesulfonate; In tetrahydrofuran; methanol; diethyl ether; N,N-dimethyl-formamide;
DOI:10.1016/0008-6215(88)85091-2