1,3-Benzenedicarboxylic acid, dipotassium salt

Base Information

• Chemical Name: 1,3-Benzenedicarboxylic acid, dipotassium salt
• CAS No.: 13527-17-8
• Molecular Formula: C₈H₄O₄*2K
• Molecular Weight: 242.314
• Mol file: 13527-17-8.mol

Synonyms:

Chemical Property of 1,3-Benzenedicarboxylic acid, dipotassium salt

Chemical Property:

• PSA: 80.26000
• LogP: -1.58640

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-Benzenedicarboxylic acid, dipotassium salt

There total 2 articles about 1,3-Benzenedicarboxylic acid, dipotassium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isophthalic acid (121-91-5) → dipotassium 1,3-benzenedicarboxylate (13527-17-8,15898-14-3,34434-54-3)

Guidance literature:

With potassium hydroxide; In water;

DOI:10.1021/jo500276h

Reference yield:

→ dipotassium 1,3-benzenedicarboxylate (13527-17-8,15898-14-3,34434-54-3)

Guidance literature:

aus Kaliumbenzoat durch Transcarboxylierung;

Reference yield: 70.0%

nickel(II) perchlorate hexahydrate + dipotassium 1,3-benzenedicarboxylate (13527-17-8,15898-14-3,34434-54-3) + 4,4,5,5-tetramethylimidazoline-1-oxyl-2-p-pyridyl-3-oxide (38987-16-5) → [Ni(2-(4'-pyridinyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)2(isophthalate)(H2O)]n

Guidance literature:

In methanol; water; aq. K-salt soln. was added to MeOH soln. of 1 equiv. of Ni-salt and 2 equiv. of N-compd., stirring at room temp. for 4 h; soln. was filtered, slow evapn. at room temp., elem. anal.;

DOI:10.1002/zaac.200500436

upstream raw materials:

isophthalic acid

Downstream raw materials:

isophthalic acid

terephthalic acid

potassium terephthalate

Refernces

• 1、 Beck, Christie L.,Winter, Arthur H.. "Noncovalent catch and release of carboxylates in water". . p. 3152 - 3158. Retrieved 2014/05/06.