trans-Fe(CO)3(PPh₂H)2

Base Information

Chemical Name:trans-Fe(CO)3(PPh₂H)2
CAS No.:40697-11-8
Molecular Formula:C₂₇H₂₂FeO₃P₂
Molecular Weight:512.264
Hs Code.:

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Chemical Property of trans-Fe(CO)3(PPh₂H)2

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Technology Process of trans-Fe(CO)3(PPh₂H)2

There total 5 articles about trans-Fe(CO)3(PPh₂H)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 191211-67-3
Fe(CO)4(P(C₆H₅)2CO(CH₂)3CH₃)

: 18399-66-1,38967-68-9
Fe(CO)4(PH(C₆H₅)2)

: 18399-67-2,40697-11-8
trans-Fe(CO)3(PPh₂H)2

Guidance literature:: With KOH; In methanol; byproducts: potassium pentanoate; Ar-atmosphere; addn. of 2 equiv. KOH to Fe-complex soln. at 0°C, warming to 20°C (after 0.5 h); evapn., extn. into THF, filtration, evapn.;
DOI:10.1016/S0022-328X(98)01223-6

Reference yield: 66.0%

: 16940-66-2
sodium tetrahydroborate

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 829-85-6
diphenylphosphane

: 40697-11-8
trans-Fe(CO)3(PPh₂H)2

Guidance literature:: In butan-1-ol; byproducts: H2; (N2); addn. of Fe(CO)5 to a stirred mixt. of PPh2H and NaBH4 and reflux the mixt. after gas evolution for 2 h; then cooling the mixt. to room temp. and placing it in a freezer at 5°C for 12 h;; filtration and washing (CH3OH) of the resulting ppt.; treatment with CH2Cl2 and filtration again; collecting of the product by filtration after addn. of CH3OH and standing of the mixt. in a freezer for several hours;;
DOI:10.1021/om00102a006

Reference yield: 40.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 829-85-6
diphenylphosphane

: 18399-67-2,40697-11-8
trans-Fe(CO)3(PPh₂H)2

Guidance literature:: In hexane; Irradiation (UV/VIS); under N2, to hexane soln. of Fe-complex was added 2 equiv of ligand, irradiated for 22 h with stirring; filtered;