Fe₃H₂(CO)8(P(C₆H₅)2)2

Base Information

• Chemical Name: Fe₃H₂(CO)8(P(C₆H₅)2)2
• CAS No.: 89993-76-0
• Molecular Formula: C₃₂H₂₂Fe₃O₈P₂
• Molecular Weight: 764.01
• Mol file: 89993-76-0.mol

Synonyms:

Chemical Property of Fe₃H₂(CO)8(P(C₆H₅)2)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe₃H₂(CO)8(P(C₆H₅)2)2

There total 1 articles about Fe₃H₂(CO)8(P(C₆H₅)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

((Ph3P)2N)2(Fe4(CO)13) + diphenylphosphane (829-85-6) → Fe3H2(CO)8(P(C6H5)2)2 (89993-76-0) + Fe(CO)4(PH(C6H5)2) (18399-66-1,38967-68-9)

Guidance literature:

With trifluoroacetic acid; In tetrahydrofuran; protonation by excess CF3COOH slurry ((Ph3P)2N)2(Fe4(CO)13) in THF at 273 K in the presence Ph2PH and warming to room temp.; chromy. on Florisil (eluant heptane-toluene 50:50);

DOI:10.1039/c39840000099

Reference yield:

Fe3H2(CO)8(P(C6H5)2)2 (89993-76-0) → Fe3(CO)9(μ3-P-C6H5)2 (38903-71-8)

Guidance literature:

With CO; In n-heptane; byproducts: C6H6; CO purging through a soln. of Fe complex at 60°C with IR and (31)P NMR monitoring; the reaction is complete within 3 h; not isolated, identified by IR and NMR spectra;

Reference yield:

Fe3H2(CO)8(P(C6H5)2)2 (89993-76-0) → Fe3(4+)*9CO*2PC6H5(2-)=Fe3(CO)9(PC6H5)2

Guidance literature:

With CO; In not given; solns. (μ-H)2Fe3(CO)8(μ-PPh2)2 treated with CO gas (1 atm, 297 K);

DOI:10.1039/c39840000099

upstream raw materials:

diphenylphosphane

Downstream raw materials:

Fe3(CO)9(μ3-P-C6H5)2