[Mn(1-6-η-C7H7(Ph))(CO)3][BF4]

Base Information

• Chemical Name: [Mn(1-6-η-C7H7(Ph))(CO)3][BF4]
• CAS No.: 62795-82-8
• Molecular Formula: BF₄*C₁₆H₁₂MnO₃
• Molecular Weight: 394.012

Synonyms:

Chemical Property of [Mn(1-6-η-C7H7(Ph))(CO)3][BF4]

Chemical Property:

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Technology Process of [Mn(1-6-η-C7H7(Ph))(CO)3][BF4]

There total 1 articles about [Mn(1-6-η-C7H7(Ph))(CO)3][BF4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Mn(1-5-η-C7H8(Ph-6-endo))(CO)3] + trityl tetrafluoroborate (341-02-6) → [Mn(1-6-η-C7H7(Ph))(CO)3][BF4] (62795-82-8) + [Mn(1-6-η-C7H7(Ph))(CO)3][BF4] (62768-81-4)

Guidance literature:

In dichloromethane; N2-atmosphere; refluxing (3 h, pptn.); not isolated, detd. by (1)H-NMR spectroscopy;

DOI:10.1039/DT9770000001

Reference yield: 35.0%

[Mn(1-6-η-C7H7(Ph))(CO)3][BF4] (62795-82-8) + [Mn(1-6-η-C7H7(Ph))(CO)3][BF4] (62768-81-4) + methyllithium (917-54-4) → [Mn(1-5-η-C7H7(Me-6-exo)(Ph-1))(CO)3] + [Mn(1-5-η-C7H7(Me-7-exo)(Ph-6-endo))(CO)3]

Guidance literature:

With water; In diethyl ether; N2-atmosphere; addn. of MeLi to suspn. of Mn-complex (0°C), stirring (1.5 h), then 12 h (room temp.), hydrolysis; extn. (Et2O), drying (over MgSO4), solvent removal (reduced pressure), repeated chromy. (light petroleum), sublimation (50°C, 1 E-2 mm Hg); elem. anal.;

DOI:10.1039/DT9770000001

Reference yield:

[Mn(1-6-η-C7H7(Ph))(CO)3][BF4] (62795-82-8) + [Mn(1-6-η-C7H7(Ph))(CO)3][BF4] (62768-81-4) + sodium methylate (124-41-4) → [Mn(1-5-η-C7H7(Ph-1)(OMe-6-exo))(CO)3]

Guidance literature:

With methanol; In methanol; N2-atmosphere; stirring (room temp., 20 min); solvent removal, repeated chromy.;

DOI:10.1039/DT9770000001

upstream raw materials:

trityl tetrafluoroborate

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