(R)-(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO₃

Base Information

• Chemical Name: (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO₃
• CAS No.: 307928-35-4
• Molecular Formula: C₃₇H₂₈O₃P₂Pt
• Molecular Weight: 777.655
• Mol file: 307928-35-4.mol

Synonyms:

Chemical Property of (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO₃

There total 2 articles about (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(P(C6H5)2)2C12H8PtCl2*CH2Cl2 (874397-88-3) + silver carbonate → (P(C6H5)2)2C12H8PtO2CO (307928-35-4,874432-97-0)

Guidance literature:

In dichloromethane; byproducts: AgCl; to a soln. of complex in wet CH2Cl2 was added Ag2CO3, the mixt. was stirred in darkness for 3 h; filtered, pptd. by addn. of hexane, recrystd. from CH2Cl2-hexane; elem.anal.;

DOI:10.1021/om000629a

Reference yield:

(R)-2,2'-bis(trifluoromethanesulfonylamino)-1,1'-binaphthyl (55442-11-0,143131-81-1) + (2,2'-bis(diphenylphosphanyl)biphenyl)PtCO3 → (S,R)-(2,2'-bs(diphenylphosphanyl)biphenyl)(2,2'-bis(trifluoromethanesulfonylamido)-1,1'-binaphthyl)platinum(II) (916073-86-4) + (R)-(2,2'-bis(diphenylphosphanyl)biphenyl)PtCO3 (307928-35-4,874432-97-0)

Guidance literature:

In ⁽²⁾H₈-toluene; reaction at temp. lower than 50 °C; detd. by NMR;

DOI:10.1002/anie.200502682

Reference yield: 47.0%

HOCHC6H5CHC6H5NHO2SCF3 + (P(C6H5)2)2C12H8PtO2CO (307928-35-4,874432-97-0) → (P(C6H5)2)2C12H8PtOCHC6H5CHC6H5NO2SCF3

Guidance literature:

In dichloromethane; a mixt. in CH2Cl2 was stirred at room temp. for 1 h; the solven was removed, dissolved in CH2Cl2, filtered, pptd. by addn. of hexane, recrystd. from CH2Cl2-hexane; elem. anal.;

DOI:10.1021/om000629a

upstream raw materials:

(P(C₆H₅)2)2C₁₂H₈PtCl₂*CH₂Cl₂

(R)-2,2'-bis(trifluoromethanesulfonylamino)-1,1'-binaphthyl

Downstream raw materials:

(S)-(2,2'-bs(diphenylphosphanyl)biphenyl)dichloroplatinum(II)