[mer-Co(H)(SPh)2(PMe₃)3]

Base Information

Chemical Name:[mer-Co(H)(SPh)2(PMe₃)3]
CAS No.:953089-65-1
Molecular Formula:C₂₁H₃₈CoP₃S₂
Molecular Weight:506.579
Hs Code.:

Synonyms:

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Chemical Property of [mer-Co(H)(SPh)2(PMe₃)3]

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Technology Process of [mer-Co(H)(SPh)2(PMe₃)3]

There total 3 articles about [mer-Co(H)(SPh)2(PMe₃)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 55516-89-7
chlorotris(trimethylphosphane)cobalt(I)

: 108-98-5
thiophenol

: 953089-65-1
[mer-Co(H)(SPh)2(PMe₃)3]

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; byproducts: HCl; Et2O soln. of thiophenol at -80°C was combined with soln. of n-BuLi in hexane, after 1 h Co complex and thiophenol were added; after 2 h mixt. was filtered off, and filtrate at -20°C afforded crystals; elem. anal.;
DOI:10.1016/j.jorganchem.2007.06.031

Reference yield: 27.0%

: 33152-37-3
tetrakis(trimethylphosphine)cobalt⁽⁰⁾

: 108-98-5
thiophenol

: 953089-65-1
[mer-Co(H)(SPh)2(PMe₃)3]

Guidance literature:: In pentane; soln. was Co complex at -80°C was combined with soln. of thiophenol, mixt. was warmed up to 20°C; slight turbidity was filtered off, and from soln. at 4°C after concn. of mother liquor crystals were obtained; elem. anal.;
DOI:10.1016/j.jorganchem.2007.06.031

Reference yield: 20.0%

: methyltetrakis(trimethylphosphine)cobalt(I)

: 108-98-5
thiophenol

: 953089-65-1
[mer-Co(H)(SPh)2(PMe₃)3]

: 953089-66-2
[cobalt(tyimethylphosphine)₂(phenylthiolate)]₂

Guidance literature:: In diethyl ether; soln. of Co complex at -80°C was combined with soln. of thiophenol under vigorous stirring, mixt. was kept stirring for 15 h at 20°C; volatiles were removed in vac., residue was extd. with pentane, one complex was collected at 4°C, crystn. of mother liquor at -21°C afforded crystals; elem. anal.;
DOI:10.1016/j.jorganchem.2007.06.031