3,3'-DIMETHOXYAZOXYBENZENE

Base Information

• Chemical Name: 3,3'-DIMETHOXYAZOXYBENZENE
• CAS No.: 13556-81-5
• Molecular Formula: C₁₄H₁₄N₂O₃
• Molecular Weight: 258.277
• DSSTox Substance ID: DTXSID80483392
• Mol file: 13556-81-5.mol

Synonyms:bis(3-methoxyphenyl)-diazene;bis-(3-methoxy-phenyl)-diazene-N-oxide;3,3'-dimethoxyazoxybenzene;3,3'-Dimethoxy-azoxybenzol;Bis-(3-methoxy-phenyl)-diazen-N-oxid;Diazene, bis(3-methoxyphenyl)-, 1-oxide;3,3'-azoxyanisole;Diazene,bis(3-methoxyphenyl)-,1-oxide;m.m'-Azoxyanisol;

Chemical Property of 3,3'-DIMETHOXYAZOXYBENZENE

Chemical Property:

• PSA: 59.57000
• LogP: 4.15270
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 258.10044231
• Heavy Atom Count: 19
• Complexity: 309

Purity/Quality:

99% ^*data from raw suppliers

3,3''-Dimethoxyazoxybenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=CC(=C1)N=[N+](C2=CC(=CC=C2)OC)[O-]

Technology Process of 3,3'-DIMETHOXYAZOXYBENZENE

There total 10 articles about 3,3'-DIMETHOXYAZOXYBENZENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

→ bis-(3-methoxy-phenyl)-diazene-N-oxide (13556-81-5,71297-96-6)

Guidance literature:

With dihydrogen peroxide; In acetone; at 60 ℃; for 5h; Green chemistry;

Reference yield: 89.0%

3-nitroanisole (555-03-3) → bis-(3-methoxy-phenyl)-diazene-N-oxide (13556-81-5,71297-96-6)

Guidance literature:

3-nitroanisole; With sodium tetrahydroborate; palladium diacetate; In ethanol; dichloromethane; water; at 20 ℃;

With oxygen; In ethanol; dichloromethane; water;

DOI:10.1039/c9gc03957k

Reference yield: 85.0%

m-Anisidine (536-90-3,918666-97-4) → bis-(3-methoxy-phenyl)-diazene-N-oxide (13556-81-5,71297-96-6)

Guidance literature:

With 2,2,2-Trifluoroacetophenone; dihydrogen peroxide; acetonitrile; In ethanol; at 20 ℃; for 18h; Green chemistry;

DOI:10.1039/c6gc03174a

upstream raw materials:

3-nitroanisole

m-Anisidine

4-bromo-3-nitroanizole

Downstream raw materials:

1,2-bis(3-methoxyphenyl)diazene

4-(3-Methoxyphenylazo)-2-methoxyphenol

2-(3-Methoxyphenylaza)-6-methoxyphenol

2-(3-Methoxyphenylazo)-4-methoxyphenol