Technology Process of [([N-(2,4,6-Me3C6H2)(3-NH-SC4H2-2-)]2PPh))ZrI2
There total 3 articles about [([N-(2,4,6-Me3C6H2)(3-NH-SC4H2-2-)]2PPh))ZrI2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
toluene;
under N2 or Ar; to a stirred toluene soln. of Zr-contg. compd. (1.28 mmol) was added Me3SiI (12.8 mmol) dropwise; stirring overnight; the react. mixt. was taken to dryness; the compd. was collected on a frit, washed with pentane, and dried; elem. anal.;
DOI:10.1021/om900612n
- Guidance literature:
-
In
toluene;
under N2 or Ar; to a stirred toluene soln. of Zr-contg. compd. (2.23 mmol) was added Me3SiI (22.3 mmol) dropwise; stirring for 3 h; the react. mixt. was taken to dryness; the compd. was collected on a frit, washed with pentane, and dried; elem. anal.;
DOI:10.1021/om900612n
- Guidance literature:
-
In
toluene;
byproducts: HNMe2; under N2 or Ar; Zr(NMe2)4 (1.85 mmol) and a ligand (1.85 mmol) were mixed together; addn. of toluene; Me3SiI (18.5 mmol) was added dropwise; stirring for 3 h; the react. mixt. was taken to dryness; the ppt. was collected on a frit with Celite and washed with pentane; extn. with toluene; toluene was removed in vac.; elem. anal.;
DOI:10.1021/om900612n
