tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II)

Base Information

• Chemical Name: tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II)
• CAS No.: 56179-29-4
• Molecular Formula: C₅₆H₄₅Cl₄O₂P₃Ru₂
• Molecular Weight: 1186.85
• Mol file: 56179-29-4.mol

Synonyms:

Chemical Property of tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II)

There total 4 articles about tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

P(C6H5)3CH2C6H5(1+)*Ru(2+)*C7H8*CO*3Cl(1-)=[P(C6H5)3CH2C6H5][Ru(C7H8)(CO)Cl3] → tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II) (56179-29-4)

Guidance literature:

With triphenylphosphine; In dichloromethane; byproducts: (Ph3PCH2Ph)Cl; equimolar amts., refluxing under N2 for 12 h; volume reduction, Et2O addn., filtration off of Ph3PBzCl, pptn. on pentane addn.; product mixt. (dinuclear:trinuclear complex = 67:33) not sepd., detd. by (31)P-NMR spectroscopy;

DOI:10.1039/DT9760002121

Reference yield:

carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II) (61989-21-7) → tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II) (56179-29-4)

Guidance literature:

In dichloromethane; byproducts: PPh3; repeated slow evapn. of CH2Cl2 from solvent mixt. (water bath, several h; pptn.); filtration, washing (EtOH, Et2O); isomer mixt. not sepd., detd. by (31)P-NMR spectroscopy; elem. anal.;

DOI:10.1039/DT9760002121

Reference yield:

ag-dicarbonyl-tri-μ-chloro-b-trichlorostanniotris(triphenylphosphine)diruthenium(II) → tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II) (56179-29-4)

Guidance literature:

In not given; byproducts: SnCl2; in soln.; not isolated, detd. by (31)P-NMR spectroscopy;

DOI:10.1039/DT9780000076

upstream raw materials:

carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II)