carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II)

Base Information

• Chemical Name: carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II)
• CAS No.: 61989-21-7
• Molecular Formula: C₃₈H₃₄Cl₂O₂P₂Ru
• Molecular Weight: 756.61
• Mol file: 61989-21-7.mol

Synonyms:

Chemical Property of carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II)

There total 1 articles about carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Ru(CO)Cl2(NN-dimethylformamide)(PPh3)2] → carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II) (61989-21-7)

Guidance literature:

With methanol; In methanol; dichloromethane; recrystn. from hot CH2Cl2/MeOH; washing (Et2O); elem. anal.;

DOI:10.1039/DT9760002121

Reference yield: 70.0%

carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II) (61989-21-7) + tetraphenylarsonium chloride hydrochloride (73003-83-5) → tetraphenylarsonium carbonyl(trichloro)bis(triphenylphosphine)ruthenate(II)-acetone (1/1)

Guidance literature:

With triphenylphosphine; In acetone; two-fold excess of Ph4AsCl*HCl, shaking for 4 h (pptn.); filtration, washing (water, MeOH, Et2O), drying (vac., 40°C); elem. anal.;

DOI:10.1039/DT9760002121

Reference yield:

carbonyldichloro(methanol)bis(triphenylphosphine)ruthenium(II) (61989-21-7) → tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II) (56179-29-4)

Guidance literature:

In dichloromethane; byproducts: PPh3; repeated slow evapn. of CH2Cl2 from solvent mixt. (water bath, several h; pptn.); filtration, washing (EtOH, Et2O); isomer mixt. not sepd., detd. by (31)P-NMR spectroscopy; elem. anal.;

DOI:10.1039/DT9760002121

Downstream raw materials:

tri-μ-chloro-dicarbonylchlorotetrakis(triphenylphosphine)diruthenium(II)