[Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Base Information

Chemical Name:[Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate
CAS No.:80006-29-7
Molecular Formula:C₅₆H₆₆N₄P₂Re*F₆P
Molecular Weight:1188.29
Hs Code.:

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Chemical Property of [Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

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Technology Process of [Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

There total 8 articles about [Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 17084-13-8
potassium hexafluorophosphate

: 12103-40-1
bis(triphenylphosphine)-rhenium heptahydride

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 80006-29-7
[Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Guidance literature:: In methanol; byproducts: H2; under N2, slurry of Re complex in methanol treated with excess of tert-butyl isocyanide, mixt. refluxed for 3 h, solvent removed under reduced pressure, residue treated with KPF6-satd. acetone, stirred for 2 h; filtered, filtrate evapd., residue washed with water and diethyl ether,dried under vac., elem. anal.;

Reference yield: 55.0%

: 17084-13-8
potassium hexafluorophosphate

: 25702-61-8
ReH₅(P(C₆H₅)3)2(NH₂C₆H₁₁)

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 80006-29-7
[Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Guidance literature:: In tetrahydrofuran; under N2, soln. of Re complex and tert-butyl isocyanide in THF refluxedfor 4 d, solvent evapd. under reduced pressure, residue stirred with KPF6-ethanol slurry for 3 h; filtrate slowly evapd., crystals sepd., washed with water and diethyl ether, dried in vac.;

Reference yield: 55.0%

: 17084-13-8
potassium hexafluorophosphate

: 12104-75-5,122169-15-7
pentahydridotris(triphenylphosphane)Re(V)

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 80006-29-7
[Re(tert-butyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Guidance literature:: In tetrahydrofuran; under N2, soln. of Re complex and tert-butyl isocyanide in THF refluxedfor 4 d, solvent evapd. under reduced pressure, residue stirred with KPF6-ethanol slurry for 3 h; filtrate slowly evapd., crystals sepd., washed with water and diethyl ether, dried in vac.;