(tert-butylamido)bis(μ-tert-butylimido)tri(tert-butylimido)dimanganese(VI) tetrakis(pentafluorophenyl)borate

Base Information

• Chemical Name: (tert-butylamido)bis(μ-tert-butylimido)tri(tert-butylimido)dimanganese(VI) tetrakis(pentafluorophenyl)borate
• CAS No.: 162441-15-8
• Molecular Formula: C₂₄BF₂₀*C₂₄H₅₅Mn₂N₆
• Molecular Weight: 1216.66
• Mol file: 162441-15-8.mol

Synonyms:

Chemical Property of (tert-butylamido)bis(μ-tert-butylimido)tri(tert-butylimido)dimanganese(VI) tetrakis(pentafluorophenyl)borate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (tert-butylamido)bis(μ-tert-butylimido)tri(tert-butylimido)dimanganese(VI) tetrakis(pentafluorophenyl)borate

There total 2 articles about (tert-butylamido)bis(μ-tert-butylimido)tri(tert-butylimido)dimanganese(VI) tetrakis(pentafluorophenyl)borate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

[Mn(VI)(NBu(t))2(μ-NBu(t))]2 + silver trifluoromethanesulfonate (2923-28-6) + lithium tetrakis(pentafluorophenyl)borate (2797-28-6) → (tert-butylamido)bis(μ-tert-butylimido)tri(tert-butylimido)dimanganese(VI) tetrakis(pentafluorophenyl)borate (162441-15-8)

Guidance literature:

In dichloromethane; byproducts: Ag; inert atmosphere; addn. of stoich. amts. of AgCF3SO3 and then LiB(C6F5)4 to Mn-complex, stirring (48 h); evapn. (vac.), washing (petroleum), extn. into Et2O, crystn. on layering with petroleum; or extn. into THF, filtration, crystn. on addn. of Et2O and cooling to -22°C for 24 h; elem. anal.;

DOI:10.1039/DT9950000937

Reference yield: 45.0%

(tetrahydrofuran)sodium bis[(μ-tert-butylimido)di(tert-butylimido)manganate(V,VI)] + lithium tetrakis(pentafluorophenyl)borate (2797-28-6) → (tert-butylamido)bis(μ-tert-butylimido)tri(tert-butylimido)dimanganese(VI) tetrakis(pentafluorophenyl)borate (162441-15-8)

Guidance literature:

With air; In tetrahydrofuran; addn. of stoich. amt. of LiB(C6F5)4 to Mn-complex, stirring (6 h); evapn. (vac.), washing (petroleum), extn. into Et2O, crystn. on layering with petroleum; or extn. into THF, filtration, crystn. on addn. of Et2O and cooling to -22°C for 24 h;

DOI:10.1039/DT9950000937

upstream raw materials:

lithium tetrakis(pentafluorophenyl)borate

silver trifluoromethanesulfonate