C₃₄H₄₁NO₁₀

Base Information

• Chemical Name: C₃₄H₄₁NO₁₀
• CAS No.: 1447802-21-2
• Molecular Formula: C₃₄H₄₁NO₁₀
• Molecular Weight: 623.7
• Mol file: 1447802-21-2.mol

Synonyms:

Chemical Property of C₃₄H₄₁NO₁₀

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₄H₄₁NO₁₀

There total 6 articles about C₃₄H₄₁NO₁₀ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C26H27IO9 → C34H41NO10 (1447802-21-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 1 h / 0 - 20 °C

2: diisopropyl-carbodiimide; dmap / dichloromethane

With dmap; 1,8-diazabicyclo[5.4.0]undec-7-ene; diisopropyl-carbodiimide; In dichloromethane;

DOI:10.1021/jo400467g

Reference yield:

methyl 1,2,4-tri-O-benzoyl-3-O-benzyl-β-L-idopyranurate (1447801-85-5) → C34H41NO10 (1447802-21-2)

Guidance literature:

Multi-step reaction with 4 steps

1.1: hydrogen bromide / dichloromethane; acetic acid / 3 h / 0 °C

1.2: 20 h / 20 °C / Inert atmosphere

2.1: trimethyltin(IV) hydroxide / toluene / 1 h / 100 °C / Microwave irradiation

2.2: 60 °C / Microwave irradiation

3.1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 5 h / 20 °C

4.1: diisopropyl-carbodiimide; dmap / dichloromethane

With dmap; hydrogen bromide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; trimethyltin(IV) hydroxide; diisopropyl-carbodiimide; In dichloromethane; acetic acid; toluene;

DOI:10.1021/jo400467g

Reference yield:

methyl 3-O-benzyl-L-idopyranosyluronate (87326-77-0,87326-78-1) → C34H41NO10 (1447802-21-2)

Guidance literature:

Multi-step reaction with 5 steps

1.1: dmap; pyridine / dichloromethane / -40 - 20 °C

2.1: hydrogen bromide / dichloromethane; acetic acid / 3 h / 0 °C

2.2: 20 h / 20 °C / Inert atmosphere

3.1: trimethyltin(IV) hydroxide / toluene / 1 h / 100 °C / Microwave irradiation

3.2: 60 °C / Microwave irradiation

4.1: 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; dmap / dichloromethane / 5 h / 20 °C

5.1: diisopropyl-carbodiimide; dmap / dichloromethane

With pyridine; dmap; hydrogen bromide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; trimethyltin(IV) hydroxide; diisopropyl-carbodiimide; In dichloromethane; acetic acid; toluene;

DOI:10.1021/jo400467g

upstream raw materials:

methyl 3-O-benzyl-L-idopyranosyluronate

methyl 1,2,4-tri-O-benzoyl-3-O-benzyl-β-L-idopyranurate

(2R,3S,4S,5R,6S)-5-Benzoyloxy-4-benzyloxy-3-(4-oxo-pentanoyloxy)-6-phenylsulfanyl-tetrahydro-pyran-2-carboxylic acid methyl ester

methyl 4-O-benzoyl-3-O-benzyl-1,2-O-[(1-pent-4-enyloxy)-benzylidene]-β-L-idopyranuronate