dimethylsulfoxonium [2-⁽¹⁴⁾C]2-phenyl-2-oxoethylide

Base Information

• Chemical Name: dimethylsulfoxonium [2-⁽¹⁴⁾C]2-phenyl-2-oxoethylide
• CAS No.: 1313403-82-5
• Molecular Formula: C₁₀H₁₂O₂S
• Molecular Weight: 198.259
• Mol file: 1313403-82-5.mol

Synonyms:

Chemical Property of dimethylsulfoxonium [2-⁽¹⁴⁾C]2-phenyl-2-oxoethylide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dimethylsulfoxonium [2-⁽¹⁴⁾C]2-phenyl-2-oxoethylide

There total 1 articles about dimethylsulfoxonium [2-⁽¹⁴⁾C]2-phenyl-2-oxoethylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[carboxyl-14C]-methyl benzoate (18615-08-2) + trimethyl sulfoxonium chloride (5034-06-0) → dimethylsulfoxonium [2-(14)C]2-phenyl-2-oxoethylide (1313403-82-5)

Guidance literature:

trimethyl sulfoxonium chloride; With potassium tert-butylate; In tetrahydrofuran; at 20 - 70 ℃; for 2h; Inert atmosphere;

[carboxyl-14C]-methyl benzoate; In tetrahydrofuran; at 20 ℃;

DOI:10.1002/jlcr.1858

Reference yield:

dimethylsulfoxonium [2-(14)C]2-phenyl-2-oxoethylide (1313403-82-5) → 2-chloro-[carbonyl-14C]acetophenone

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; 1,4-dioxane; at 90 ℃; for 2h;

DOI:10.1002/jlcr.1858

upstream raw materials:

[carboxyl-14C]-methyl benzoate

trimethyl sulfoxonium chloride