5,5''-Bis(4-methoxyphenyl)-2,2':6',2''-terpyridine

Base Information

Chemical Name:5,5''-Bis(4-methoxyphenyl)-2,2':6',2''-terpyridine
CAS No.:135943-44-1
Molecular Formula:C29H23N3O2
Molecular Weight:445.521
Hs Code.:
DSSTox Substance ID:DTXSID201229798
Nikkaji Number:J2.143.291A
Mol file:135943-44-1.mol

Synonyms:5,5''-Bis(4-methoxyphenyl)-2,2':6',2''-terpyridine;DTXSID201229798;135943-44-1

Suppliers and Price of 5,5''-Bis(4-methoxyphenyl)-2,2':6',2''-terpyridine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5,5''-Bis(4-methoxyphenyl)-2,2':6',2''-terpyridine

Chemical Property:

XLogP3:5.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:6
Exact Mass:445.17902698
Heavy Atom Count:34
Complexity:552

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=CC=C(C=C1)C2=CN=C(C=C2)C3=NC(=CC=C3)C4=NC=C(C=C4)C5=CC=C(C=C5)OC

Technology Process of 5,5''-Bis(4-methoxyphenyl)-2,2':6',2''-terpyridine

There total 5 articles about 5,5''-Bis(4-methoxyphenyl)-2,2':6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 848566-45-0
C₂₅H₁₉N₇O₂

: 121-46-0
bicyclo[2.2.1]hepta-2,5-diene

: 135943-44-1
5,5''-di(4-methoxyphenyl)-2,2':6',2''-terpyridine

Guidance literature:: In o-xylene; for 48h; Heating;
DOI:10.1016/j.tetlet.2005.01.020

Reference yield:

: 135943-45-2
5,5''-di(4-hydroxyphenyl)-2,2':6',2''-terpyridine

: 74-83-9
methyl bromide

: 135943-44-1
5,5''-di(4-methoxyphenyl)-2,2':6',2''-terpyridine

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 12h;
DOI:10.1039/b709730a

Reference yield:

: 67867-35-0
(E)-2-(4-methoxyphenyl)-2-oxoacetaldehyde oxime

: 135943-44-1
5,5''-di(4-methoxyphenyl)-2,2':6',2''-terpyridine

Guidance literature:: Multi-step reaction with 3 steps

1: N₂H₄*H₂O / ethanol / 20 °C

2: 68 percent / acetic acid / 0.02 h / Heating

3: 65 percent / o-xylene / 48 h / Heating

With hydrazine hydrate; In ethanol; o-xylene; acetic acid; 3: aza-Diels-Alder reaction;
DOI:10.1016/j.tetlet.2005.01.020