1,3(4H)-Pyridinedicarboxylic acid, 5,6-dihydro-4-oxo-, 3-methyl 1-(phenylmethyl) ester

Base Information

Chemical Name:1,3(4H)-Pyridinedicarboxylic acid, 5,6-dihydro-4-oxo-, 3-methyl 1-(phenylmethyl) ester
CAS No.:135967-34-9
Molecular Formula:C15H15NO5
Molecular Weight:289.288
Hs Code.:
Mol file:135967-34-9.mol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1,3(4H)-Pyridinedicarboxylic acid, 5,6-dihydro-4-oxo-, 3-methyl 1-(phenylmethyl) ester

Chemical Property:

Purity/Quality:

Safty Information:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

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Technology Process of 1,3(4H)-Pyridinedicarboxylic acid, 5,6-dihydro-4-oxo-, 3-methyl 1-(phenylmethyl) ester

There total 5 articles about 1,3(4H)-Pyridinedicarboxylic acid, 5,6-dihydro-4-oxo-, 3-methyl 1-(phenylmethyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 140176-28-9
1-(carbobenzyloxy)-3-carbomethoxy-3-(phenylselenyl)-4-piperidone

: 135967-34-9
1-(carbobenzyloxy)-3-carbomethoxy-5,6-dihydro-4-pyridone

Guidance literature:: With dihydrogen peroxide; In dichloromethane; water; at 0 ℃; Yield given;
DOI:10.1021/jo00036a008

Reference yield:

: 140176-27-8
1-oxo-1,3-piperidinedicarboxylic acid 1-benzyl ester 3-methyl ester

: 135967-34-9
1-(carbobenzyloxy)-3-carbomethoxy-5,6-dihydro-4-pyridone

Guidance literature:: With Phenylselenyl bromide; dihydrogen peroxide; sodium hydride; Multistep reaction; 1.) THF, 2.) CH₂Cl₂;
DOI:10.1016/S0040-4039(00)79755-3

Reference yield:

: 71486-53-8
methyl 4-oxo-3-piperidinecarboxylate hydrochloride

: 135967-34-9
1-(carbobenzyloxy)-3-carbomethoxy-5,6-dihydro-4-pyridone

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / Et₃N / CH₂Cl₂ / 1.) 0 deg C, 0.5 h, 2.) r.t., 1 h

2: 1.) NaH / 1.) THF, r.t., 45 min, 2.a) THF, -50 deg C, 2 h, b) r.t., 1 h

3: 30percent H₂O₂ / CH₂Cl₂; H₂O / 0 °C

With dihydrogen peroxide; sodium hydride; triethylamine; In dichloromethane; water;
DOI:10.1021/jo00036a008