chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I)

Base Information

• Chemical Name: chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I)
• CAS No.: 136776-52-8
• Molecular Formula: C₅₂H₄₇ClO₂P₃Rh
• Molecular Weight: 935.224
• Mol file: 136776-52-8.mol

Synonyms:

Chemical Property of chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I)

There total 1 articles about chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Wilkinson's catalyst (14694-95-2) + (C6H5)2PO2CCH2CH2CH3 (136819-53-9) → chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) (136776-53-9) + chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) (136776-52-8,136776-53-9)

Guidance literature:

DOI:10.1039/DT9910001929

Reference yield: 95.0%

chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) (136776-52-8,136776-53-9) → (diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) hexafluorophosphate (136842-01-8)

Guidance literature:

With thallium(I) hexafluorophosphate; In tetrahydrofuran; stirred 1 h, filtered, evapd. to dryness in vac.;

DOI:10.1039/DT9910001929

Reference yield:

chloro(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) (136776-52-8,136776-53-9) + potassium crotanoate (59471-15-7) → but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I) (136776-57-3)

Guidance literature:

In dichloromethane; stirred for 3 h, filtered the excess of K(O2CCHCHMe, evapd. in vac., light petroleum added, filtered off and dried in vac.;

DOI:10.1039/DT9910001929

upstream raw materials:

Wilkinson's catalyst

(C₆H₅)2PO₂CCH₂CH₂CH₃

Downstream raw materials:

but-2-enoato(diphenylphosphino but-2-enoate)(triphenylphosphine)rhodium(I)

(diphenylphosphino butyrate)bis(triphenylphosphine)rhodium(I) hexafluorophosphate