Bis(trimethylsilyl)-3-pentadecylcatechol

Base Information

• Chemical Name: Bis(trimethylsilyl)-3-pentadecylcatechol
• CAS No.: 76014-95-4
• Molecular Formula: C₂₇H₅₂O₂Si₂
• Molecular Weight: 464.88
• Mol file: 76014-95-4.mol

Synonyms:

Chemical Property of Bis(trimethylsilyl)-3-pentadecylcatechol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Bis(trimethylsilyl)-3-pentadecylcatechol

There total 8 articles about Bis(trimethylsilyl)-3-pentadecylcatechol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

azelaic acid (123-99-9,26776-28-3) → Bis(trimethylsilyl)-3-pentadecylcatechol (76014-95-4)

Guidance literature:

Multi-step reaction with 5 steps

1: 78 g / bromine, red mercuric oxide / various solvent(s) / 3 h / 80 - 90 °C

2: 22 percent / butyl-lithium / hexane; tetrahydrofuran / 4 h / Heating

3: 70 percent / butyl-lithium / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 24 h / Ambient temperature

4: 0.4 g / hydrogen / 5percent palladium-barium sulphate / ethyl acetate

5: 0.57 g / CDCl₃ / 96 h / 50 °C

With n-butyllithium; hydrogen; bromine; mercury(II) oxide; Pd-BaSO₄; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; chloroform-d1; hexane; ethyl acetate;

DOI:10.1039/P19800002331

Reference yield:

1,7-dibromoheptane (4549-31-9) → Bis(trimethylsilyl)-3-pentadecylcatechol (76014-95-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 22 percent / butyl-lithium / hexane; tetrahydrofuran / 4 h / Heating

2: 70 percent / butyl-lithium / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 24 h / Ambient temperature

3: 0.4 g / hydrogen / 5percent palladium-barium sulphate / ethyl acetate

4: 0.57 g / CDCl₃ / 96 h / 50 °C

With n-butyllithium; hydrogen; Pd-BaSO₄; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; chloroform-d1; hexane; ethyl acetate;

DOI:10.1039/P19800002331

Reference yield:

3-(pentadec-8-ynyl)veratrole (76014-94-3) → Bis(trimethylsilyl)-3-pentadecylcatechol (76014-95-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 0.4 g / hydrogen / 5percent palladium-barium sulphate / ethyl acetate

2: 0.57 g / CDCl₃ / 96 h / 50 °C

With hydrogen; Pd-BaSO₄; In chloroform-d1; ethyl acetate;

DOI:10.1039/P19800002331

upstream raw materials:

trimethylsilyl iodide

1,2-dimethoxy-3-pentadecyl-benzene

azelaic acid

1,7-dibromoheptane

Downstream raw materials:

3-pentadecylcatechol