(4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate

Base Information

Chemical Name:(4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate
CAS No.:1390672-63-5
Molecular Formula:C₂F₃O₂*C₁₅H₁₁F₃IN₂O
Molecular Weight:532.181
Hs Code.:

Synonyms:

Suppliers and Price of (4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate

There total 4 articles about (4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

: 100-66-3
methoxybenzene

: 76-05-1
trifluoroacetic acid

: 210107-38-3
3-(4-iodophenyl)-3-(trifluoromethyl)-3H-diazirine

: 1390672-63-5
(4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate

Guidance literature:: trifluoroacetic acid; 3-(4-iodophenyl)-3-(trifluoromethyl)-3H-diazirine; With potassium peroxymonosulfate; In chloroform; at 0 - 20 ℃;

methoxybenzene; With trifluoroacetic acid; In dichloromethane; at -10 - 20 ℃; for 2h;
DOI:10.1021/jm300631e

Reference yield:

: 23516-84-9
2,2,2-trifluoro-1-(4-iodophenyl)ethan-1-one

: 1390672-63-5
(4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate

Guidance literature:: Multi-step reaction with 4 steps

1.1: pyridine; hydroxylamine hydrochloride / methanol / 2 h / Reflux

2.1: pyridine / dichloromethane / 12 h / 20 °C / Cooling with ice

3.1: ammonia / methanol; dichloromethane / 48 h / -50 - 20 °C

3.2: -20 °C

4.1: potassium peroxymonosulfate / chloroform / 0 - 20 °C

4.2: 2 h / -10 - 20 °C

With pyridine; potassium peroxymonosulfate; hydroxylamine hydrochloride; ammonia; In methanol; dichloromethane; chloroform;
DOI:10.1021/jm300631e

Reference yield:

: 210107-35-0
oxime 4'-iodo-2,2,2-trifluoroacetophenone

: 1390672-63-5
(4-methoxyphenyl)-[4-(3-trifluoromethyl-3H-diazirin-3-yl)phenyl]iodonium trifluoroacetate

Guidance literature:: Multi-step reaction with 3 steps

1.1: pyridine / dichloromethane / 12 h / 20 °C / Cooling with ice

2.1: ammonia / methanol; dichloromethane / 48 h / -50 - 20 °C

2.2: -20 °C

3.1: potassium peroxymonosulfate / chloroform / 0 - 20 °C

3.2: 2 h / -10 - 20 °C

With pyridine; potassium peroxymonosulfate; ammonia; In methanol; dichloromethane; chloroform;
DOI:10.1021/jm300631e