Hf(CH₂C₆H₅)2(C₇H₅N₂((CH₂)3)2N₂C₇H₅)

Base Information

Chemical Name:Hf(CH₂C₆H₅)2(C₇H₅N₂((CH₂)3)2N₂C₇H₅)
CAS No.:198290-80-1
Molecular Formula:C₃₄H₃₆HfN₄
Molecular Weight:679.177
Hs Code.:

Hf(CH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>)2(C<sub>7</sub>H<sub>5</sub>N<sub>2</sub>((CH<sub>2</sub>)3)2N<sub>2</sub>C<sub>7</sub>H<sub>5</sub>)

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Suppliers and Price of Hf(CH₂C₆H₅)2(C₇H₅N₂((CH₂)3)2N₂C₇H₅)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Hf(CH₂C₆H₅)2(C₇H₅N₂((CH₂)3)2N₂C₇H₅)

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Technology Process of Hf(CH₂C₆H₅)2(C₇H₅N₂((CH₂)3)2N₂C₇H₅)

There total 1 articles about Hf(CH₂C₆H₅)2(C₇H₅N₂((CH₂)3)2N₂C₇H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: Hf⁽⁴⁺⁾*4CH₂C₆H₅^(1-)=[Hf(CH₂C₆H₅)4]

: 84927-34-4
6,7,8,9,16,17,18,19-octahydrodicyclohepta[b,i][1,4,8,11]tetraazacyclotetradecene

: 198290-80-1
Hf(CH₂C₆H₅)2(C₇H₅N₂((CH₂)3)2N₂C₇H₅)

Guidance literature:: In pentane; inert atmosphere, absence of light; addn. of ligand to metal compd. at -30°C, stirring at 35°C for 1 h (pptn.); collection (filtration), washing (Et2O, pentane), drying; can be recrystallized by Et2O diffusion into CH2Cl2 soln. (several d);

Reference yield: 51.0%

: 198290-80-1
[Hf(tropocoronand-3,3)(benzyl)2]

: trimethylammonium tetraphenylborate

: 205115-24-8
(C₂₀H₂₂N₄)Hf(CH₂C₆H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(C₂₀H₂₂N₄)Hf(CH₂C₆H₅)]B(C₆H₅)4

Guidance literature:: In dichloromethane; N2 or Ar-atmosphere; stirring (room temp., 15 min); pptn. on ether addn. (-30°C), washing (ether, pentane), drying; elem. anal.;
DOI:10.1021/om971126g

Reference yield: 37.0%

: 198290-80-1
[Hf(tropocoronand-3,3)(benzyl)2]

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 202412-95-1
[Hf(tropocoronand-3,3)((2,6-dimethylphenyl)N=CC(benzyl)2N(2,6-dimethylphenyl))]

Guidance literature:: In toluene; N2 or Ar-atmosphere; slow addn. of excess of isocyanide to soln. of Hf-complex at -30°C over 15 min, warming to room temp., stirring for 15 min (pptn.); collection (filtration), washing (ether, pentane), drying, recrystn. (CH2Cl2:ether); NMR spectroscopy;
DOI:10.1021/om9706830