C₅₀H₅₈O₈Si

Base Information

Chemical Name:C₅₀H₅₈O₈Si
CAS No.:115352-37-9
Molecular Formula:C₅₀H₅₈O₈Si
Molecular Weight:815.091
Hs Code.:

C<sub>50</sub>H<sub>58</sub>O<sub>8</sub>Si

Synonyms:

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Chemical Property of C₅₀H₅₈O₈Si

Chemical Property:

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Technology Process of C₅₀H₅₈O₈Si

There total 22 articles about C₅₀H₅₈O₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 82740-87-2
(2R,3S,6R)-2-acetoxymethyl-6-allyl-3,6-dihydro-2H-pyran-3-yl acetate

: 115352-37-9
C₅₀H₅₈O₈Si

Guidance literature:: Multi-step reaction with 19 steps

1: 89 percent / water, trimethylamine / methanol / Ambient temperature

2: 80 percent / d,l-camphorsulfonic acid / CH₂Cl₂ / Ambient temperature

3: 1.) diborane, 2.) 2N NaOH, 30percent H₂O₂ / 1.) THF, -25 deg C, 12 h, 2.) EtOH, RT, overnight

4: pyridine / Ambient temperature

5: MeOH, Dowex 50W (H+) / 9.5 h / Ambient temperature

6: MCPBA / CHCl₃ / 5 °C

7: d,l-camphorsulfonic acid / CHCl₃

8: sodium methoxide / methanol; tetrahydrofuran / 5 °C

9: 1.) DMSO, (COCl)2, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 2.) CH₂Cl₂, -78 deg C, 10 min.

10: PPTS / CH₂Cl₂ / Ambient temperature

11: 1.) sodium hydride / 1.) DMF, 5 deg C, overnight, 2.) DMF, 70 deg C, 3.5 h

12: 1.) potassium hydride / 1.) DMF, RT, 10 min; 2.) DMF, RT, 30 min.

13: 98 percent / 0.5N HCl / tetrahydrofuran / 3 h / Ambient temperature

14: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min; 2.) THF, -78 deg C, 30 min.

15: 1.) DMSO, oxalyl chloride, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 15 min; 2.) CH₂Cl₂, -78 to 0 deg C

16: 1.) aluminium foil, 2percent HgCl₂ / 1.) MeOH, ether, 30 sec; 2.) THF, H₂O, 60 deg C, overnight

17: EtOH, acetic acid / 72 h / Heating

18: hydrogen / 25percent Pd/C / ethanol; acetic acid / 15 h / Ambient temperature

19: pyridine / 65 °C

With pyridine; hydrogenchloride; methanol; sodium hydroxide; n-butyllithium; oxalyl dichloride; ethanol; Dowex 50W (H+); camphor-10-sulfonic acid; water; hydrogen; dihydrogen peroxide; sodium methylate; pyridinium p-toluenesulfonate; potassium hydride; sodium hydride; acetic acid; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; aluminium; mercury dichloride; diborane; trimethylamine; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol; dichloromethane; chloroform; acetic acid;
DOI:10.1016/S0040-4020(01)86916-7

Reference yield:

: 95791-07-4
(2R,3S,6R)-6-allyl-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol

: 115352-37-9
C₅₀H₅₈O₈Si

Guidance literature:: Multi-step reaction with 18 steps

1: 80 percent / d,l-camphorsulfonic acid / CH₂Cl₂ / Ambient temperature

2: 1.) diborane, 2.) 2N NaOH, 30percent H₂O₂ / 1.) THF, -25 deg C, 12 h, 2.) EtOH, RT, overnight

3: pyridine / Ambient temperature

4: MeOH, Dowex 50W (H+) / 9.5 h / Ambient temperature

5: MCPBA / CHCl₃ / 5 °C

6: d,l-camphorsulfonic acid / CHCl₃

7: sodium methoxide / methanol; tetrahydrofuran / 5 °C

8: 1.) DMSO, (COCl)2, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 2.) CH₂Cl₂, -78 deg C, 10 min.

9: PPTS / CH₂Cl₂ / Ambient temperature

10: 1.) sodium hydride / 1.) DMF, 5 deg C, overnight, 2.) DMF, 70 deg C, 3.5 h

11: 1.) potassium hydride / 1.) DMF, RT, 10 min; 2.) DMF, RT, 30 min.

12: 98 percent / 0.5N HCl / tetrahydrofuran / 3 h / Ambient temperature

13: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min; 2.) THF, -78 deg C, 30 min.

14: 1.) DMSO, oxalyl chloride, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 15 min; 2.) CH₂Cl₂, -78 to 0 deg C

15: 1.) aluminium foil, 2percent HgCl₂ / 1.) MeOH, ether, 30 sec; 2.) THF, H₂O, 60 deg C, overnight

16: EtOH, acetic acid / 72 h / Heating

17: hydrogen / 25percent Pd/C / ethanol; acetic acid / 15 h / Ambient temperature

18: pyridine / 65 °C

With pyridine; hydrogenchloride; methanol; sodium hydroxide; n-butyllithium; oxalyl dichloride; ethanol; Dowex 50W (H+); camphor-10-sulfonic acid; hydrogen; dihydrogen peroxide; sodium methylate; pyridinium p-toluenesulfonate; potassium hydride; sodium hydride; acetic acid; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; aluminium; mercury dichloride; diborane; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol; dichloromethane; chloroform; acetic acid;
DOI:10.1016/S0040-4020(01)86916-7

Reference yield:

: 115369-17-0
3-((1aS,2R,3aR,7aR,7bS)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalen-2-yl)-propionaldehyde

: 115352-37-9
C₅₀H₅₈O₈Si

Guidance literature:: Multi-step reaction with 10 steps

1: PPTS / CH₂Cl₂ / Ambient temperature

2: 1.) sodium hydride / 1.) DMF, 5 deg C, overnight, 2.) DMF, 70 deg C, 3.5 h

3: 1.) potassium hydride / 1.) DMF, RT, 10 min; 2.) DMF, RT, 30 min.

4: 98 percent / 0.5N HCl / tetrahydrofuran / 3 h / Ambient temperature

5: 1.) n-BuLi / 1.) THF, -78 deg C, 30 min; 2.) THF, -78 deg C, 30 min.

6: 1.) DMSO, oxalyl chloride, 2.) triethylamine / 1.) CH₂Cl₂, -78 deg C, 15 min; 2.) CH₂Cl₂, -78 to 0 deg C

7: 1.) aluminium foil, 2percent HgCl₂ / 1.) MeOH, ether, 30 sec; 2.) THF, H₂O, 60 deg C, overnight

8: EtOH, acetic acid / 72 h / Heating

9: hydrogen / 25percent Pd/C / ethanol; acetic acid / 15 h / Ambient temperature

10: pyridine / 65 °C

With pyridine; hydrogenchloride; n-butyllithium; oxalyl dichloride; ethanol; hydrogen; pyridinium p-toluenesulfonate; potassium hydride; sodium hydride; acetic acid; dimethyl sulfoxide; triethylamine; aluminium; mercury dichloride; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; acetic acid;
DOI:10.1016/S0040-4020(01)86916-7