Benzeneoctanal, 2,3-bis(acetyloxy)-

Base Information

• Chemical Name: Benzeneoctanal, 2,3-bis(acetyloxy)-
• CAS No.: 136788-23-3
• Molecular Formula: C18H24O5
• Molecular Weight: 320.386
• Mol file: 136788-23-3.mol

Synonyms:

Chemical Property of Benzeneoctanal, 2,3-bis(acetyloxy)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzeneoctanal, 2,3-bis(acetyloxy)-

There total 6 articles about Benzeneoctanal, 2,3-bis(acetyloxy)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

3-(8-iodooctyl)catechol diacetate (136788-22-2) → 3-(8-oxooctyl)catechol diacetate (136788-23-3)

Guidance literature:

With sodium hydrogencarbonate; dimethyl sulfoxide; In benzene; at 90 ℃; for 4h;

DOI:10.1246/bcsj.64.2560

Reference yield:

1,2-dimethoxybenzene (91-16-7) → 3-(8-oxooctyl)catechol diacetate (136788-23-3)

Guidance literature:

Multi-step reaction with 5 steps

1: 1) BuLi / 1) THF, hexane, 2h, RT, 2) THF, 5h, reflux

2: 92 percent / BBr₃ / CH₂Cl₂ / 12 h / 0 deg C to RT

3: 76 percent / pyridine / 4 h / 100 °C

4: 88 percent / NaI / acetone / 3 h / 60 °C

5: 71 percent / NaHCO₃, DMSO / benzene / 4 h / 90 °C

With pyridine; n-butyllithium; boron tribromide; sodium hydrogencarbonate; dimethyl sulfoxide; sodium iodide; In dichloromethane; acetone; benzene;

DOI:10.1246/bcsj.64.2560

Reference yield:

1,8-dibromooctane (4549-32-0) → 3-(8-oxooctyl)catechol diacetate (136788-23-3)

Guidance literature:

Multi-step reaction with 5 steps

1: 1) BuLi / 1) THF, hexane, 2h, RT, 2) THF, 5h, reflux

2: 92 percent / BBr₃ / CH₂Cl₂ / 12 h / 0 deg C to RT

3: 76 percent / pyridine / 4 h / 100 °C

4: 88 percent / NaI / acetone / 3 h / 60 °C

5: 71 percent / NaHCO₃, DMSO / benzene / 4 h / 90 °C

With pyridine; n-butyllithium; boron tribromide; sodium hydrogencarbonate; dimethyl sulfoxide; sodium iodide; In dichloromethane; acetone; benzene;

DOI:10.1246/bcsj.64.2560

upstream raw materials:

3-(8-iodooctyl)catechol diacetate

1,2-dimethoxybenzene

1,8-dibromooctane

3-(8-bromooctyl)catechol

Downstream raw materials:

azelaic acid

3-<(8Z,11E,13E)-8,11,13-pentadecatrienyl>catechol

3-<(8Z,11Z)-8,11,14-pentadecatrienyl>catechol

3-<(8Z,11Z)-8,11,14-pentadecatrienyl>catechol diacetate