(S)-phenyl methoxymethyl sulfoxide

Base Information

• Chemical Name: (S)-phenyl methoxymethyl sulfoxide
• CAS No.: 128854-34-2
• Molecular Formula: C₈H₁₀O₂S
• Molecular Weight: 170.232
• Mol file: 128854-34-2.mol

Synonyms:

Chemical Property of (S)-phenyl methoxymethyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-phenyl methoxymethyl sulfoxide

There total 5 articles about (S)-phenyl methoxymethyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

methoxymethyl phenyl sulfide (13865-50-4) → Methoxymethyl phenyl sulfoxide (37559-63-0,128854-34-2,140696-20-4)

Guidance literature:

With dichlorodioxobis(triphenylphosphineoxide)molybdenum(VI); tetrabutylammonium nitrate; copper(II) nitrate; In acetonitrile; at 60 ℃; for 10h; chemoselective reaction;

DOI:10.1021/jo2001808

Reference yield: 60.0%

→ Methoxymethanesulfinyl-benzene (37559-63-0,128854-34-2,140696-20-4)

Guidance literature:

at 0 ℃; for 20h;

DOI:10.1246/bcsj.63.1316

Reference yield:

methoxymethyl phenyl sulfide (13865-50-4) → phenyl methoxymethyl sulfone (15251-78-2) + (S)-phenyl methoxymethyl sulfoxide (128854-34-2) + (R)-methoxymethyl phenyl sulfoxide (140696-20-4)

Guidance literature:

With dihydrogen peroxide; 6,6′-bis[(S)-4-isopropyloxazolin-2-y1]-2,2′-bipyridine; iron(II) chloride; In tetrahydrofuran; water; at -25 ℃; for 3h; enantioselective reaction;

DOI:10.1002/ejoc.201601597

upstream raw materials:

methoxymethyl phenyl sulfide

phenyl methoxymethyl sulfone

Downstream raw materials:

methoxymethanol

substituted benzenethiol

S-phenyl benzenethiosulfinate

methoxymethyl benzenesulfenate