Technology Process of (E)-1-(phenylsulfonyl)-1-acetoxy-3-(trichloroacetamido)-4-hexene
There total 9 articles about (E)-1-(phenylsulfonyl)-1-acetoxy-3-(trichloroacetamido)-4-hexene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
DOI:10.1021/jo00351a009
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) sodium hydride / 1.) ether, RT, 15 min, 2.) ether, a.) -10 to -15 deg C, 1 h, b.) RT, 3 h
2: 88 percent / AIBN / 12 h / 80 - 90 °C
3: sodium metaperiodate / methanol / Ambient temperature
4: 99 percent / 2,6-lutidine, TFAA / 5 h / Ambient temperature
5: 95 percent / 80-85percent m-chloroperoxybenzoic acid / CH2Cl2
With
2,6-dimethylpyridine; sodium periodate; 2,2'-azobis(isobutyronitrile); sodium hydride; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic anhydride;
In
methanol; dichloromethane;
DOI:10.1021/jo00351a009
- Guidance literature:
-
Multi-step reaction with 6 steps
1: 80 percent / benzene / 60 h / Heating
2: 100 percent / lithium aluminum hydride / diethyl ether / 16 h
3: 1.) potassium hydride / 1.) ether, RT, 15 min, 2.) ether, a.) -10 to -15 deg C, 1 h, b.) RT, 3 h
4: sodium metaperiodate / methanol / Ambient temperature
5: 99 percent / 2,6-lutidine, TFAA / 5 h / Ambient temperature
6: 95 percent / 80-85percent m-chloroperoxybenzoic acid / CH2Cl2
With
2,6-dimethylpyridine; sodium periodate; lithium aluminium tetrahydride; potassium hydride; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic anhydride;
In
methanol; diethyl ether; dichloromethane; benzene;
DOI:10.1021/jo00351a009
