1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid

Base Information

Chemical Name:1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid
CAS No.:625820-35-1
Molecular Formula:C₄₇H₇₁O₆P
Molecular Weight:763.051
Hs Code.:

Synonyms:

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Chemical Property of 1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid

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Technology Process of 1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid

There total 8 articles about 1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: ((2R,3S,4R,5R)-3,4-Bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-ylmethyl)-icosyl-phosphane

: 625820-35-1
1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid

Guidance literature:: With pyridine; water; iodine; at 20 ℃; for 72h;
DOI:10.1021/jo034475v

Reference yield:

: 629-96-9
n-eicosanol

: 625820-35-1
1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 66 percent / n-BuLi / hexane; tetrahydrofuran / 3 h / 20 °C

2: P₄-Schweshinger base / diethyl ether; hexane / 0.5 h / 20 °C

3: 35 mg / I₂; pyridine; H₂O / 72 h / 20 °C

With pyridine; n-butyllithium; P₄-Schweshinger base; water; iodine; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1021/jo034475v

Reference yield:

: 160549-10-0
2,3,5-tri-O-benzyl-D-arabinofuranose

: 625820-35-1
1-(eicosanyl)-3,4,6-tri-O-benzyl-2,5-anhydroglucityl phosphinic acid

Guidance literature:: Multi-step reaction with 6 steps

1.1: n-BuLi / tetrahydrofuran

1.2: 77 percent / tetrahydrofuran / 20 °C

2.1: 95 percent / I₂; NaHCO₃ / diethyl ether / 20 °C

3.1: 85 percent / 12 h / 156 °C

4.1: 69 percent / LiAlH₄ / diethyl ether / 0.33 h / 20 °C

5.1: P₄-Schweshinger base / diethyl ether; hexane / 0.5 h / 20 °C

6.1: 35 mg / I₂; pyridine; H₂O / 72 h / 20 °C

With pyridine; lithium aluminium tetrahydride; n-butyllithium; P₄-Schweshinger base; water; iodine; sodium hydrogencarbonate; In tetrahydrofuran; diethyl ether; hexane; 1.2: Wittig reaction;
DOI:10.1021/jo034475v