IrCl(CO)(P(p-tolyl)3)2

Base Information

• Chemical Name: IrCl(CO)(P(p-tolyl)3)2
• CAS No.: 23385-92-4
• Molecular Formula: C₄₃H₄₂ClIrOP₂
• Molecular Weight: 864.426
• Mol file: 23385-92-4.mol

Synonyms:

Chemical Property of IrCl(CO)(P(p-tolyl)3)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of IrCl(CO)(P(p-tolyl)3)2

There total 1 articles about IrCl(CO)(P(p-tolyl)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + carbon monoxide (201230-82-2) + Tri(p-tolyl)phosphine (1038-95-5,218281-19-7) → IrCl(CO)(P(p-tolyl)3)2 (23385-92-4,28195-56-4)

Guidance literature:

bis(1,5-cyclooctadiene)diiridium(I) dichloride; Tri(p-tolyl)phosphine; at 20 ℃; for 0.25h; Inert atmosphere;

carbon monoxide; for 2h; Inert atmosphere;

DOI:10.1039/d1cc02520a

Reference yield: 84.0%

IrCl(CO)(P(p-tolyl)3)2 (23385-92-4,28195-56-4) + P(C6H5)2CH2N2BHC6H4CH2P(C6H5)2 (1192763-84-0) → [IrHCl(CO)(B(NCH2P(C6H5)2)2C6H4)]

Guidance literature:

In toluene; under Ar, glovebox; B compd. added to soln. of Ir complex in toluene; mixt. stirred under reflux for 24 h; evapn.; recrystd. from THF/hexane; elem. anal.;

DOI:10.1021/om9006455

Reference yield:

IrCl(CO)(P(p-tolyl)3)2 (23385-92-4,28195-56-4) → Ir(1+)*CO*Cl(1-)*2P(C6H4CH3)3*H2=Ir(CO)(Cl)(P(C6H4CH3)3)2(H2)

Guidance literature:

With hydrogen; In N,N-dimethyl-formamide; under N2; Kinetics;

upstream raw materials:

bis(1,5-cyclooctadiene)diiridium(I) dichloride

carbon monoxide

Tri(p-tolyl)phosphine

Downstream raw materials:

Ir(CO)(Cl)2(H)(P(C₆H₄CH₃)3)2