2-bromo-1-methyl-4-tert-butyl-benzene

Base Information

• Chemical Name: 2-bromo-1-methyl-4-tert-butyl-benzene
• CAS No.: 61024-94-0
• Molecular Formula: C11H15 Br
• Molecular Weight: 227.144
• Hs Code.: 2903999090
• Mol file: 61024-94-0.mol

Synonyms:Toluene,2-bromo-4-tert-butyl- (7CI); 1-Bromo-2-methyl-5-tert-butylbenzene;1-Bromo-5-(1,1-dimethylethyl)-2-methylbenzene;2-Bromo-1-methyl-4-tert-butylbenzene; 2-Bromo-4-tert-butyltoluene; NSC 266252

Chemical Property of 2-bromo-1-methyl-4-tert-butyl-benzene

Chemical Property:

• Vapor Pressure: 0.0778mmHg at 25°C
• Boiling Point: 235.1°C at 760 mmHg
• Flash Point: 93.7°C
• PSA: 0.00000
• Density: 1.204g/cm³
• LogP: 4.05500

Purity/Quality:

97% ^*data from raw suppliers

2-Bromo-4-tert-butyl-1-methylbenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-bromo-1-methyl-4-tert-butyl-benzene

There total 11 articles about 2-bromo-1-methyl-4-tert-butyl-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-tert-butyltoluene (98-51-1) → 2-bromo-4-tert-butyl-1-methylbenzene (61024-94-0)

Guidance literature:

With bromine; iodine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1021/jacs.0c08115

Reference yield: 84.0%

4-tert-butyltoluene (98-51-1) → 2-bromo-4-tert-butyl-1-methylbenzene (61024-94-0) + 1-(bromomethyl)-4-(1,1-dimethylethyl)benzene (18880-00-7)

Guidance literature:

With sodium bromate; sodium hydrogensulfite; In water; acetonitrile; at 20 ℃; for 4h;

DOI:10.1021/jo972263q

Reference yield: 70.0%

((CH3C6H4)3PC6H3(C4H9)CH3PdBr)2 (330783-82-9,330979-75-4) + tri-tert-butyl phosphine (13716-12-6) → bis(tri-t-butylphosphine)palladium(0) (53199-31-8) + 2-bromo-4-tert-butyl-1-methylbenzene (61024-94-0)

Guidance literature:

In benzene-d6; byproducts: P(o-tol)3, biaryl, arene; in C6D6 soln. at 70°C; NMR spectroscopy; K(eq) = 2.3(3)E-3;

DOI:10.1021/ja0034592

upstream raw materials:

4-tert-butyltoluene

bromine

acetic acid

((CH₃C₆H₄)3PC₆H₃(C₄H₉)CH₃PdBr)2

Downstream raw materials:

Tris(2-methyl-5-tert.-butylphenyl)phosphin

1,8-bis(5-tert-butyl-2-methylphenyl)octane

2-Methyl-3-bromo-5-tert-butylbenzyl chloride

2-methyl-5-tert-butylbenzaldehyde

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 61024-94-0 2-bromo-1-methyl-4-tert-butyl-benzene

Send

Send

Metric Ton KG G Pound L ML

Send

Send