Fe2Cl2(μ-S-tBu)2(η(1)-η(1)-μ-Ph2PCH2CH2PPh2)

Base Information

• Chemical Name: Fe2Cl2(μ-S-tBu)2(η(1)-η(1)-μ-Ph2PCH2CH2PPh2)
• CAS No.: 622830-17-5
• Molecular Formula: C₃₄H₄₂Cl₂Fe₂P₂S₂
• Molecular Weight: 759.387
• Mol file: 622830-17-5.mol

Synonyms:

Chemical Property of Fe2Cl2(μ-S-tBu)2(η(1)-η(1)-μ-Ph2PCH2CH2PPh2)

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of Fe2Cl2(μ-S-tBu)2(η(1)-η(1)-μ-Ph2PCH2CH2PPh2)

There total 1 articles about Fe2Cl2(μ-S-tBu)2(η(1)-η(1)-μ-Ph2PCH2CH2PPh2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

{1,2-bis(diphenylphosphino)ethane}dichloroiron (41536-18-9) + 2-methylpropan-2-thiol (75-66-1) → Fe2Cl2(μ-S-tBu)2(η(1)-η(1)-μ-Ph2PCH2CH2PPh2) (622830-17-5)

Guidance literature:

With NaH; In tetrahydrofuran; under Ar, 2 equiv. of thiol and 2 equiv. of NaH were added in THF to THfsoln. of Fe-compd., stirring at ambient temp. for 2 h; solvent was stripped in vac., residue was taken in toluene, filtration through Celite, soln. was concd., n-hexane was added, ppt. was filtered off, washed with n-hexane, crystn. from toluene-n-hexane soln. (3:1, v/v)at -20 °C, elem. anal.;

DOI:10.1515/znb-2003-0418

upstream raw materials:

{1,2-bis(diphenylphosphino)ethane}dichloroiron

2-methylpropan-2-thiol