C₁₀H₁₄IPS

Base Information

• Chemical Name: C₁₀H₁₄IPS
• CAS No.: 115591-18-9
• Molecular Formula: C₁₀H₁₄IPS
• Molecular Weight: 324.165
• Mol file: 115591-18-9.mol

Synonyms:

Chemical Property of C₁₀H₁₄IPS

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₀H₁₄IPS

There total 4 articles about C₁₀H₁₄IPS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((S)-tert-Butylphosphinothioyl)-benzene (115591-16-7,115591-22-5,159684-64-7) → C10H14IPS (115591-18-9)

Guidance literature:

With N-iodo-succinimide; In benzene; for 1h; Ambient temperature;

DOI:10.1021/jo00254a024

Reference yield:

(+/-)-tert-butyl(phenyl)phosphinothioic O-acid (6002-45-5) → C10H14IPS (115591-18-9)

Guidance literature:

Multi-step reaction with 4 steps

1: diethyl ether

2: 9.2 percent / CH₂Cl₂ / -50 - 20 °C

3: 77 percent / NaBH₄ / benzene; ethanol / -20 - 20 °C

4: N-iodosuccinimide / benzene / 1 h / Ambient temperature

With sodium tetrahydroborate; N-iodo-succinimide; In diethyl ether; ethanol; dichloromethane; benzene;

DOI:10.1021/jo00254a024

Reference yield:

(Rp)-(+)-tert-Butylphenylphosphinothioic acid (54100-47-9) → C10H14IPS (115591-18-9)

Guidance literature:

Multi-step reaction with 3 steps

1: 9.2 percent / CH₂Cl₂ / -50 - 20 °C

2: 77 percent / NaBH₄ / benzene; ethanol / -20 - 20 °C

3: N-iodosuccinimide / benzene / 1 h / Ambient temperature

With sodium tetrahydroborate; N-iodo-succinimide; In ethanol; dichloromethane; benzene;

DOI:10.1021/jo00254a024

upstream raw materials:

((S)-tert-Butylphosphinothioyl)-benzene

(+/-)-tert-butyl(phenyl)phosphinothioic O-acid

(R_p)-(+)-tert-Butylphenylphosphinothioic acid

R-(-)-tert-butylphenylphosphinothioic acid O-(trifluoromethyl)sulfonyl ester

Refernces