propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside

Base Information

Chemical Name:propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside
CAS No.:165061-01-8
Molecular Formula:C₄₆H₆₄N₂O₂₃
Molecular Weight:1013.01
Hs Code.:

Synonyms:

Suppliers and Price of propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside

Chemical Property:

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Technology Process of propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside

There total 8 articles about propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 99409-32-2
ethyl-3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-1-thio-β-D-glucopyranoside

: 165061-01-8
propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 61 percent / 4A molecular sieves, MeOTf / CH₂Cl₂ / 15 h / Ambient temperature

2: 80 percent / AcOH / 0.5 h / 90 °C

3: 71 percent / 4A molecular sieves, MeOTf / CH₂Cl₂ / 12 h

4: NH₂NH₂*H₂O / ethanol / 12 h / 100 °C

5: pyridine, 4-dimethylaminopyridine / 12 h / Ambient temperature

With pyridine; dmap; 4 A molecular sieve; hydrazine hydrate; acetic acid; methyl trifluoromethanesulfonate; In ethanol; dichloromethane;
DOI:10.1016/0008-6215(94)00369-Q

Reference yield:

: 100-39-0
benzyl bromide

: 165061-01-8
propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) n-Bu₂SnO, 2.) n-Bu₄NI, 3.) aq. KF

2: 61 percent / 4A molecular sieves, MeOTf / CH₂Cl₂ / 15 h / Ambient temperature

3: 80 percent / AcOH / 0.5 h / 90 °C

4: 71 percent / 4A molecular sieves, MeOTf / CH₂Cl₂ / 12 h

5: NH₂NH₂*H₂O / ethanol / 12 h / 100 °C

6: pyridine, 4-dimethylaminopyridine / 12 h / Ambient temperature

With pyridine; dmap; potassium fluoride; 4 A molecular sieve; tetra-(n-butyl)ammonium iodide; di(n-butyl)tin oxide; hydrazine hydrate; acetic acid; methyl trifluoromethanesulfonate; In ethanol; dichloromethane;
DOI:10.1016/0008-6215(94)00369-Q

Reference yield:

: 81600-93-3
allyl 4,6-di-O-benzylidene-α-D-mannopyranoside

: 165061-01-8
propyl 2,6-bis-O-(2-acetamido-3,4,6-tri-O-acetyl-β-D-glucopyranosyl)-3-O-benzyl-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) n-Bu₂SnO, 2.) n-Bu₄NI, 3.) aq. KF

2: 61 percent / 4A molecular sieves, MeOTf / CH₂Cl₂ / 15 h / Ambient temperature

3: 80 percent / AcOH / 0.5 h / 90 °C

4: 71 percent / 4A molecular sieves, MeOTf / CH₂Cl₂ / 12 h

5: NH₂NH₂*H₂O / ethanol / 12 h / 100 °C

6: pyridine, 4-dimethylaminopyridine / 12 h / Ambient temperature

With pyridine; dmap; potassium fluoride; 4 A molecular sieve; tetra-(n-butyl)ammonium iodide; di(n-butyl)tin oxide; hydrazine hydrate; acetic acid; methyl trifluoromethanesulfonate; In ethanol; dichloromethane;
DOI:10.1016/0008-6215(94)00369-Q