cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3)

Base Information

• Chemical Name: cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3)
• CAS No.: 848997-26-2
• Molecular Formula: CF₃O₃S*C₁₉H₁₆Fe₂O₃P
• Molecular Weight: 584.072
• Mol file: 848997-26-2.mol

Synonyms:

Chemical Property of cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3)

There total 1 articles about cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

trans-[(C5H5)2Fe2(CO)2(μ-H)(μ-PHPh)] (848997-24-0,849107-66-0,849107-65-9) + trifluorormethanesulfonic acid (1493-13-6) + carbon monoxide (201230-82-2) → cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3) (848997-26-2)

Guidance literature:

In dichloromethane; byproducts: H2; acid was added to soln. of Fe complex in CH2Cl2 under CO at -48°C; soln. was stirred at room temp. for 4 h; filtered; evapd. (vac.); recrystd. (CH2Cl2 layered with ether); elem. anal.;

DOI:10.1021/om049000o

Reference yield: 78.0%

cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3) (848997-26-2) + phenylacetylene (536-74-3) → cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PPhCH=CHPh)](O3SCF3)

Guidance literature:

In dichloromethane; (vac. or N2); CH2Cl2 and PhCCH were transferred by trap-to-trap distn. to Fe complex; sealed in vac.; stand at room temp. for 10 d; filtered; evapd. (vac.); washed (CH2Cl2/hexane, 3/5); recrystd. (CH2Cl2/hexane/ether, 4/5/5.7); elem. anal.;

DOI:10.1021/om049000o

Reference yield: 65.0%

cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PHPh)](O3SCF3) (848997-26-2) + acrylic acid methyl ester (292638-85-8,9003-21-8,96-33-3) → cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PPhCH2CH2CO2Me)](O3SCF3) (848997-31-9)

Guidance literature:

In dichloromethane; (vac. or N2); CH2Cl2 and methyl acrylate were transferred by trap-to-trap distn. to Fe complex; sealed in vac.; stand at room temp. for 10 d; filtered; evapd. (vac.); washed (CH2Cl2/hexane, 3/5); recrystd. (CH2Cl2/hexane/ether, 4/5/5.7); elem. anal.;

DOI:10.1021/om049000o

upstream raw materials:

trans-[(C5H5)2Fe2(CO)2(μ-H)(μ-PHPh)]

trifluorormethanesulfonic acid

carbon monoxide

Downstream raw materials:

cis-[(C5H5)2Fe2(CO)2(μ-CO)(μ-PPhCH2CH2CO2Me)](O3SCF3)