1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate

Base Information

Chemical Name:1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate
CAS No.:1338782-07-2
Molecular Formula:BF₄*C₂₄H₂₇FeN₂S
Molecular Weight:518.209
Hs Code.:

Synonyms:

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Chemical Property of 1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate

Chemical Property:

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Technology Process of 1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate

There total 1 articles about 1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13755-29-8
sodium tetrafluoroborate

: 1338782-00-5
1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium iodide

: 1338782-07-2
1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate

Guidance literature:: In dichloromethane; water; (inert atm.); addn. of aq. soln. of NaBF4 to CH2Cl2 soln. of ferrocene deriv., stirring for 16 h; separation organic phase, extn. (CH2Cl2), washing combined CH2Cl2 solns.with water, drying over Na2SO4, filtration, concg., addn. of ether, fil tration through celite, washing with ether, extn. (CH2Cl2), evapn., elem. anal.;
DOI:10.1039/c1nj20224c

Reference yield: 86.0%

: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

: 1338782-07-2
1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate

: [(η5-C5(CH3)5)Rh(III)Cl(1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)](tetrafluoroborate)

Guidance literature:: With Ag₂O; In dichloromethane; (inert atm.); heating mixt. of rhodium compd., ferrocenium deriv. and Ag2O in dry CH2Cl2 at reflux for 40 h in dark; filtration through celite, evapn. in vac., chromy. (neutral alumina deactivated with 6-8%, CH2Cl2/methanol (95:5)), elem. anal.;
DOI:10.1039/c1nj20224c

Reference yield: 85.0%

: 52462-29-0
[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

: 1338782-07-2
1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazolium tetrafluoroborate

: [(η6-p-cymene)Ru(II)Cl(1-(β-(ferrocenylthio)ethyl)-3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)](tetrafluoroborate)

Guidance literature:: With Ag₂O; In dichloromethane; (inert atm.); heating mixt. of ruthenium compd., ferrocenium deriv. and Ag2O in dry CH2Cl2 at reflux for 40 h in dark; filtration through celite, concg. in vac., addn. of hexane, filtration through celite, washing with hexane, extn. (CH2Cl2), chromy. (neutral alumina deactivated with 6-8% H2O, CH2Cl2/methanol (95:5)), elem. anal.;
DOI:10.1039/c1nj20224c