anizyldi(n-butyl)tinhydride

Base Information

• Chemical Name: anizyldi(n-butyl)tinhydride
• CAS No.: 1338248-41-1
• Molecular Formula: C₁₅H₂₆OSn
• Molecular Weight: 341.081
• Mol file: 1338248-41-1.mol

Synonyms:

Chemical Property of anizyldi(n-butyl)tinhydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of anizyldi(n-butyl)tinhydride

There total 1 articles about anizyldi(n-butyl)tinhydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

lithium aluminium tetrahydride (16853-85-3) + anizyldi(n-butyl)tinchloride (1169881-75-7) → anizyldi(n-butyl)tinhydride (1338248-41-1)

Guidance literature:

In diethyl ether; Sn-compd. dissolved in Et2O, added to LiAlH4 in Et2O, heated under reflux for 4 h, cooled to room temp.; hydroquinone, 20% sodium potassium tartrate in H2O and H2O added slowly stepwise, etheral layer separated, aqueous layer extracted with ether, combined organic extracts washed with H2O, dried over MgSO4, filtered, concentrated in vac.;

DOI:10.1016/j.jorganchem.2011.07.004

Reference yield: 82.0%

anizyldi(n-butyl)tinhydride (1338248-41-1) + poly((9,9-bis(6'-bromohexyl)fluoren-2,7-diyl)-alt-co-(benzen-1,4-diyl)) → poly((9,9-bis(6'-dibutyl(4-methoxyphenyl)stannylhexyl)fluoren-2,7-diyl)-alt-co-(benzen-1,4-diyl))

Guidance literature:

With C₄H₉Li; NHi-Pr₂; In tetrahydrofuran; hexane; BuLi in n-hexane added dropwise to NHi-Pr2 in dry THF at -78°C, stirred for 1 h, warmed to -60°C, Sn-compd. added dropwise, stirred for 1 h, added to Br-compd. in dry THF at -60°C, warmed to roomtemp., stirred for 24 h; CH3OH added, stirred, filtered, washed with CH3OH, dried in vac. at 50°C, dissolved in CH2Cl2, activated charcoal added, filtered, CH3OH added, stirred for 2 h, filtered, washed with CH3OH, dried in vac.;

DOI:10.1016/j.jorganchem.2011.07.004

upstream raw materials:

lithium aluminium tetrahydride

anizyldi(n-butyl)tinchloride