anizyldi(n-butyl)tinchloride

Base Information

• Chemical Name: anizyldi(n-butyl)tinchloride
• CAS No.: 1169881-75-7
• Molecular Formula: C₁₅H₂₅ClOSn
• Molecular Weight: 375.526
• Mol file: 1169881-75-7.mol

Synonyms:

Chemical Property of anizyldi(n-butyl)tinchloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of anizyldi(n-butyl)tinchloride

There total 1 articles about anizyldi(n-butyl)tinchloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

Sn(n-Bu)2(C6H4OMe-p)2 (374805-30-8) + dibutyltin chloride (683-18-1) → anizyldi(n-butyl)tinchloride (1169881-75-7)

Guidance literature:

In neat (no solvent); other Radiation; mixt. of SnBu2(C6H4OMe)2 (1 equiv.) and SnBu2Cl2 (2 equiv.) was heated at 100°C for 60 min in microwave oven; chromd. (alumina, ether);

DOI:10.1021/om900326g

Reference yield: 85.0%

lithium aluminium tetrahydride (16853-85-3) + anizyldi(n-butyl)tinchloride (1169881-75-7) → anizyldi(n-butyl)tinhydride (1338248-41-1)

Guidance literature:

In diethyl ether; Sn-compd. dissolved in Et2O, added to LiAlH4 in Et2O, heated under reflux for 4 h, cooled to room temp.; hydroquinone, 20% sodium potassium tartrate in H2O and H2O added slowly stepwise, etheral layer separated, aqueous layer extracted with ether, combined organic extracts washed with H2O, dried over MgSO4, filtered, concentrated in vac.;

DOI:10.1016/j.jorganchem.2011.07.004

Reference yield:

anizyldi(n-butyl)tinchloride (1169881-75-7) → poly((9,9-bis(6'-chlorodibutylstannylhexyl)fluoren-2,7-diyl)-alt-co-(benzen-1,4-diyl))

Guidance literature:

Multi-step reaction with 3 steps

1: diethyl ether

2: C₄H₉Li; NHi-Pr₂ / hexane; tetrahydrofuran

3: diethyl ether; dichloromethane

With C₄H₉Li; NHi-Pr₂; In tetrahydrofuran; diethyl ether; hexane; dichloromethane;

DOI:10.1016/j.jorganchem.2011.07.004

upstream raw materials:

Sn(n-Bu)2(C₆H₄OMe-p)2

dibutyltin chloride

Downstream raw materials:

anizyldi(n-butyl)tinhydride