[((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]

Base Information

Chemical Name:[((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]
CAS No.:1207722-55-1
Molecular Formula:C₅₆H₈₀Al₂Li₂N₄O₄
Molecular Weight:941.121
Hs Code.:

Synonyms:

Suppliers and Price of [((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]

There total 1 articles about [((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 16853-85-3
lithium aluminium tetrahydride

: 245093-30-5
(CyNH-o-C₆H₄)2O

: 1207722-55-1
[((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]

Guidance literature:: In tetrahydrofuran; byproducts: H2; (N2); addn. of LiAlH4 to THF soln. of diamine deriv. at -35°C, warming to room temp., stirring at room temp. for 20 h; filtration, evapn., washing with toluene, elem. anal.;
DOI:10.1039/b911802k

Reference yield: 63.0%

: 1207722-55-1
[((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]

: [((CyN-o-C₆H₄)2O)AlH(tetrahydrofuran)]

Guidance literature:: With CH₂Cl₂; In dichloromethane; byproducts: LiCl, CH3Cl; (N2); stirring CH2Cl2 soln. of aluminium compd. at room temp. overnight; filtration, evapn., recrystn. (pentane/CH2Cl2 (9:1)) at -5°C, elem. anal.;
DOI:10.1039/b911802k

Reference yield: 45.0%

: 1207722-55-1
[((κ2N,N':κ2N,O-(CyN-o-C6H4)2O)AlH(μ-H)Li(tetrahydrofuran))2]

: 100-52-7
benzaldehyde

: 1207722-46-0
[(κ2N,N':κ1O-(CyN-o-C6H4)2O)AlH(μ-benzyloxide)Li(tetrahydrofuran)2]

Guidance literature:: In tetrahydrofuran; (N2); addn. of 1 equiv. of benzaldehyde to THF soln. of aluminium compd.at -35°C, warming to room temp., stirring overnight; evapn., recrystn. (pentane/THF (5:1)) at -35°C, elem. anal.;
DOI:10.1039/b911802k