PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3)

Base Information

• Chemical Name: PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3)
• CAS No.: 622829-60-1
• Molecular Formula: C₅₈H₄₇MnO₃P₄Pd
• Molecular Weight: 1077.26
• Mol file: 622829-60-1.mol

Synonyms:

Chemical Property of PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3)

There total 2 articles about PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

(bis(diphenylphosphino)methane)palladium(II) dichloride (38425-01-3) + bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn) (90739-53-0) → PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3) (622829-60-1)

Guidance literature:

In toluene; Mn2-complex was added to a suspn. of PdCl2(dppm) in toluene under N2, the mixt. was refluxed under vigorous stirring for 4 h; filtd., evapd., residue was dissolved in acetone and chromd. on silica TLC plates (eluent 3:7 acetone-hexane); elem. anal.;

DOI:10.1016/S0020-1693(02)01546-3

Reference yield:

(bis(diphenylphosphino)methane)palladium(II) dichloride (38425-01-3) + Na[Mn2(CO)8(μ-PPh2)] → PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3) (622829-60-1)

Guidance literature:

DOI:10.1016/S0020-1693(02)01546-3

Reference yield: 46.0%

PdMn(μ-PPh2)(μ-dppm)(CO)3(PPh3) (622829-60-1) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → PdMn(μ-PPh2)(μ-dppm)(CO)3(Ph2PCH2CH2P(=O)Ph2)

Guidance literature:

In toluene; dppe was added to a soln. of PdMn-complex in toluene under N2, the mixt.was refluxed for 24 h; filtd., evapd. in vacuo, residue chromd. on silica TLC plates (eluent 3:7 acetone-hexane); elem. anal.;

DOI:10.1016/S0020-1693(02)01546-3

upstream raw materials:

(bis(diphenylphosphino)methane)palladium(II) dichloride

bis(triphenylphosphine)iminium μ-diphenylphosphido-bis(tetracarbonylmanganate)(Mn-Mn)