bis[P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato]nickel

Base Information

• Chemical Name: bis[P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato]nickel
• CAS No.: 1042980-41-5
• Molecular Formula: C₃₂H₄₀N₂NiO₆P₄S₂
• Molecular Weight: 795.396
• Mol file: 1042980-41-5.mol

Synonyms:

Chemical Property of bis[P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato]nickel

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato]nickel

There total 1 articles about bis[P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato]nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinic acid potassium salt + nickel dichloride (83864-14-6) → bis[P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato]nickel (1042980-41-5)

Guidance literature:

In tetrahydrofuran; ethanol; byproducts: KCl; under Ar; mixt. of K salt of ligand and NiCl2 (molar ratio 2:1) in THF-EtOH stirred at reflux for 8 h; solvent removed in vac.; treated with CH2Cl2; filtered; filtrate concd. in vac.; ppt. isolated; elem. anal.;

DOI:10.1016/j.poly.2008.04.006

Reference yield: 99.0%

P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinic acid potassium salt + bis[P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato]nickel (1042980-41-5) → potassium [tris(P,P-diethoxy-P'P'-diphenyl-P'-thioimidodiphosphinato)nickel(II)]

Guidance literature:

In methanol; mixt. of K salt of ligand and Ni complex (molar ratio 1:1) in MeOH stirred at room temp. for 24 h; solvent removed in vac.; elem. anal.;

DOI:10.1016/j.poly.2008.04.006

upstream raw materials:

nickel dichloride