chlorophenylplatinum{1,3-bis(diphenylphosphino)propane}

Base Information

• Chemical Name: chlorophenylplatinum{1,3-bis(diphenylphosphino)propane}
• CAS No.: 96806-44-9
• Molecular Formula: C₃₃H₃₁ClP₂Pt
• Molecular Weight: 720.09
• Mol file: 96806-44-9.mol

Synonyms:

Chemical Property of chlorophenylplatinum{1,3-bis(diphenylphosphino)propane}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorophenylplatinum{1,3-bis(diphenylphosphino)propane}

There total 2 articles about chlorophenylplatinum{1,3-bis(diphenylphosphino)propane} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[PtCl(COC6H5)(((C6H5)2PCH2)2CH2)] (96806-48-3) → [1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) + [PtCl(C6H5)(((C6H5)2PCH2)2CH2)] (96806-44-9)

Guidance literature:

In chloroform; under N2, CHCl3 soln. of educt refluxed for several days;

DOI:10.1021/om00128a010

Reference yield:

phenylchloro(1,5-cyclooctadiene)platinum(II) + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → [PtCl(C6H5)(((C6H5)2PCH2)2CH2)] (96806-44-9)

Guidance literature:

In chloroform; under N2, CHCl3 soln. of PtClPh(cod) added to soln. of ligand in CHCl3,stirred for 1.5 h; rotary concd., ether added, solid filtered, washed with ether, dried bysuction; elem. anal.;

DOI:10.1021/om00128a010

Reference yield: 87.0%

[Bu3NMe]2[SnB11H11] + chlorophenylplatinum{1,3-bis(diphenylphosphino)propane} (96806-44-9) → [Bu3MeN][(1,3-bis(diphenylphosphanyl)propane)PtPh(stanna-closo-dodecaborate)]

Guidance literature:

In dichloromethane; byproducts: Bu3MeNCl; all manipulations under dry N2; soln. of Pt compd. reacted with Sn compd. at room temp., stirred for 24 h; solvent evapd., solid washed with water, elem. anal.;

DOI:10.1002/1099-0682(200209)2002:9<2261::AID-EJIC2261>3.0.CO;2-6

upstream raw materials:

1,3-bis-(diphenylphosphino)propane

[PtCl(COC₆H₅)(((C₆H₅)2PCH₂)2CH₂)]

Downstream raw materials:

chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}