chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}

Base Information

• Chemical Name: chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}
• CAS No.: 96806-48-3
• Molecular Formula: C₃₄H₃₁ClOP₂Pt
• Molecular Weight: 748.1
• Mol file: 96806-48-3.mol

Synonyms:

Chemical Property of chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane}

There total 2 articles about chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorophenylplatinum{1,3-bis(diphenylphosphino)propane} (96806-44-9) → chlorophenyl(CO)platinum{1,3-bis(diphenylphosphino)propane} (96806-48-3)

Guidance literature:

With carbon monoxide; In chloroform-d1; React. occurs under Ar atmosphere.; Monitoring of react. by NMR.;

DOI:10.1021/om00101a006

Reference yield:

chlorophenyl(CO)platinum(cod) (76705-02-7) + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → [PtCl(COC6H5)(((C6H5)2PCH2)2CH2)] (96806-48-3)

Guidance literature:

In chloroform; under N2, CHCl3 soln. of Pt complex and ligand stirred for 1.5 h; rotary concd., ether added slowly, ppt. removed by filtration, filtrateconcd., ether added, ppt. filtered, washed with ether, dried by suction; elem. anal.;

DOI:10.1021/om00128a010

Reference yield:

[PtCl(COC6H5)(((C6H5)2PCH2)2CH2)] (96806-48-3) → [1,3-bis(diphenylphosphino)propane]dichloroplatinum(II) (59329-00-9) + [PtCl(C6H5)(((C6H5)2PCH2)2CH2)] (96806-44-9)

Guidance literature:

In chloroform; under N2, CHCl3 soln. of educt refluxed for several days;

DOI:10.1021/om00128a010

upstream raw materials:

chlorophenylplatinum{1,3-bis(diphenylphosphino)propane}

chlorophenyl(CO)platinum(cod)

1,3-bis-(diphenylphosphino)propane

Downstream raw materials:

[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

[PtCl(C₆H₅)(((C₆H₅)2PCH₂)2CH₂)]