cinnamyl-1-ferrocenoate

Base Information

• Chemical Name: cinnamyl-1-ferrocenoate
• CAS No.: 1225386-59-3
• Molecular Formula: C₂₀H₁₈FeO₂
• Molecular Weight: 346.209
• Mol file: 1225386-59-3.mol

Synonyms:

Chemical Property of cinnamyl-1-ferrocenoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cinnamyl-1-ferrocenoate

There total 1 articles about cinnamyl-1-ferrocenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

1-(ferrocenylcarbonyl)-1H-benzotriazole (1163726-65-5) + 3-Phenylpropenol (104-54-1) → cinnamyl-1-ferrocenoate (1225386-59-3)

Guidance literature:

With NaH; In tetrahydrofuran; byproducts: 1H-benzotriazole; FcCOBt (1 equiv.) soln. added dropwise under N2 to C6H5CHCHCH2OH (1 equiv.) soln. in presence of NaH, stirred for 30 min at 25°C; solvent evapd. (vac.), ethylacetate added, washed with 20% Na2CO3 aq. soln., organic layer sepd., dried over MgSO4, solvent evapd., chromd. (silica gel, ethylacetate/hexanes 1:5 eluent), solvent evapd., recrystd. (ethylacetate/hexane 1:5); elem. anal.;

DOI:10.1016/j.jorganchem.2009.11.015

upstream raw materials:

1-(ferrocenylcarbonyl)-1H-benzotriazole

3-Phenylpropenol