[(η5-C5Me5)Ru(κ2-P,C-P(i-Pr)2C9H5N(Me)CH)(diphenylphosphine)]

Base Information

• Chemical Name: [(η5-C5Me5)Ru(κ2-P,C-P(i-Pr)2C9H5N(Me)CH)(diphenylphosphine)]
• CAS No.: 1085803-38-8
• Molecular Formula: C₃₉H₄₉NP₂Ru
• Molecular Weight: 694.842
• Mol file: 1085803-38-8.mol

Synonyms:

Chemical Property of [(η5-C5Me5)Ru(κ2-P,C-P(i-Pr)2C9H5N(Me)CH)(diphenylphosphine)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η5-C5Me5)Ru(κ2-P,C-P(i-Pr)2C9H5N(Me)CH)(diphenylphosphine)]

There total 1 articles about [(η5-C5Me5)Ru(κ2-P,C-P(i-Pr)2C9H5N(Me)CH)(diphenylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

[(η5-C5Me5)Ru(κ3-P,C,C'-P(i-Pr)2C9H5N(Me)CH)] + diphenylphosphane (829-85-6) → [(η5-C5Me5)Ru(κ2-P,C-P(i-Pr)2C9H5N(Me)CH)(diphenylphosphine)] (1085803-38-8)

Guidance literature:

In benzene; (N2); using Schlenk techniques; addn. of PHPh2 to glass vial containing of magnetically stirred soln. of (C5Me5)Ru(P(i-Pr)2C9H5N(Me)CH) in C6H6;sealing with PTFE-lined cap; stirring for 48 h; monitoring by NMR; removal of solvent and other volatile materials in vac., trituration with pentane; removal of pentane in vac.; elem. anal.;

DOI:10.1021/om800740z

Reference yield: 91.0%

[(η5-C5Me5)Ru(κ2-P,C-P(i-Pr)2C9H5N(Me)CH)(diphenylphosphine)] (1085803-38-8) → [(η5-C5Me5)Ru(CHNHMe)(κ2-P,P-P(i-Pr)2C9H5PPh2)]

Guidance literature:

In benzene; (N2); charging Schlenk flask with (C5Me5)Ru(P(i-Pr)2C9H5N(Me)CH)(PHPh2),magnetic stirbar and C6H6; sealing; heating at 50°C under stirri ng for 7 ds; removal of solvent and other materials in vac., trituration with pentane; removal of pentane in vac., elem. anal.;

DOI:10.1021/om800740z

upstream raw materials:

diphenylphosphane